Preparation of tetrasubstituted furans via intramolecular wittig reactions with phosphorus ylides as intermediates

Tzu Ting Kao; Siang En Syu; Yi Wun Jhang; Wenwei Lin

doi:10.1021/ol101080q

Preparation of tetrasubstituted furans via intramolecular wittig reactions with phosphorus ylides as intermediates

Tzu Ting Kao, Siang En Syu, Yi Wun Jhang, Wenwei Lin^*

^*此作品的通信作者

化學系

研究成果: 雜誌貢獻 › 期刊論文 › 同行評審

98 引文斯高帕斯（Scopus）

摘要

Novel preparation of tetrasubstituted furans, starting from the Michael acceptors, tributylphosphine, and acyl chlorides, is realized. A broad range of highly functional furans can be efficiently generated in one step at room temperature within 10 min to 21 h in moderate to high yields (60-99%). The reaction was proposed to proceed via intramolecular Wittig-type reactions, using phosphorus ylides as intermediates.

原文	英語
頁（從 - 到）	3066-3069
頁數	4
期刊	Organic Letters
卷	12
發行號	13
DOIs	https://doi.org/10.1021/ol101080q
出版狀態	已發佈 - 2010 7月 2

ASJC Scopus subject areas

生物化學
物理與理論化學
有機化學

存取文件

10.1021/ol101080q

其它文件與鏈接

CCDC 769770: Experimental Crystal Structure Determination
Kao, T. (Creator), Syu, S. (Creator), Jhang, Y. (Creator) & Lin, W. (Creator), Unknown Publisher, 2011
DOI: 10.5517/cctv09y, http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/cctv09y&sid=DataCite
資料集: Dataset
CCDC 769220: Experimental Crystal Structure Determination
Kao, T. (Creator), Syu, S. (Creator), Jhang, Y. (Creator) & Lin, W. (Creator), Unknown Publisher, 2011
DOI: 10.5517/ccttfkl, http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/ccttfkl&sid=DataCite
資料集: Dataset
CCDC 768638: Experimental Crystal Structure Determination
Kao, T. (Creator), Syu, S. (Creator), Jhang, Y. (Creator) & Lin, W. (Creator), Unknown Publisher, 2011
DOI: 10.5517/cctsts5, http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/cctsts5&sid=DataCite
資料集: Dataset

引用此

@article{9801d6869a804d1da05879efc2e45592,

title = "Preparation of tetrasubstituted furans via intramolecular wittig reactions with phosphorus ylides as intermediates",

abstract = "Novel preparation of tetrasubstituted furans, starting from the Michael acceptors, tributylphosphine, and acyl chlorides, is realized. A broad range of highly functional furans can be efficiently generated in one step at room temperature within 10 min to 21 h in moderate to high yields (60-99%). The reaction was proposed to proceed via intramolecular Wittig-type reactions, using phosphorus ylides as intermediates.",

author = "Kao, {Tzu Ting} and Syu, {Siang En} and Jhang, {Yi Wun} and Wenwei Lin",

year = "2010",

month = jul,

day = "2",

doi = "10.1021/ol101080q",

language = "English",

volume = "12",

pages = "3066--3069",

journal = "Organic Letters",

issn = "1523-7060",

publisher = "American Chemical Society",

number = "13",

}

TY - JOUR

T1 - Preparation of tetrasubstituted furans via intramolecular wittig reactions with phosphorus ylides as intermediates

AU - Kao, Tzu Ting

AU - Syu, Siang En

AU - Jhang, Yi Wun

AU - Lin, Wenwei

PY - 2010/7/2

Y1 - 2010/7/2

N2 - Novel preparation of tetrasubstituted furans, starting from the Michael acceptors, tributylphosphine, and acyl chlorides, is realized. A broad range of highly functional furans can be efficiently generated in one step at room temperature within 10 min to 21 h in moderate to high yields (60-99%). The reaction was proposed to proceed via intramolecular Wittig-type reactions, using phosphorus ylides as intermediates.

AB - Novel preparation of tetrasubstituted furans, starting from the Michael acceptors, tributylphosphine, and acyl chlorides, is realized. A broad range of highly functional furans can be efficiently generated in one step at room temperature within 10 min to 21 h in moderate to high yields (60-99%). The reaction was proposed to proceed via intramolecular Wittig-type reactions, using phosphorus ylides as intermediates.

UR - http://www.scopus.com/inward/record.url?scp=77954097756&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=77954097756&partnerID=8YFLogxK

U2 - 10.1021/ol101080q

DO - 10.1021/ol101080q

M3 - Article

C2 - 20521775

AN - SCOPUS:77954097756

SN - 1523-7060

VL - 12

SP - 3066

EP - 3069

JO - Organic Letters

JF - Organic Letters

IS - 13

ER -

Preparation of tetrasubstituted furans via intramolecular wittig reactions with phosphorus ylides as intermediates

摘要

ASJC Scopus subject areas

存取文件

其它文件與鏈接

指紋

資料集

CCDC 769770: Experimental Crystal Structure Determination

CCDC 769220: Experimental Crystal Structure Determination

CCDC 768638: Experimental Crystal Structure Determination

引用此