Preparation of polyfunctional arynes via 2-magnesiated diaryl sulfonates

Ioannis Sapountzis*, Wenwei Lin, Markus Fischer, Paul Knochel

*此作品的通信作者

研究成果: 雜誌貢獻期刊論文同行評審

78 引文 斯高帕斯(Scopus)

摘要

The synthetic potential of arynes can be exploited through a new method for their generation from functionalized aryl magnesium reagents and controlled reaction. Arynes with functional groups such as ester, nitrile, ketone, or nitro groups, or with a quinolyl skeleton, can be formed from polyfunctionalized 2-iodo aryl 4-chlorobenezenesulfonates and trapped in 68-93% yield with furan (see scheme).

原文英語
頁(從 - 到)4364-4366
頁數3
期刊Angewandte Chemie - International Edition
43
發行號33
DOIs
出版狀態已發佈 - 2004 8月 20
對外發佈

ASJC Scopus subject areas

  • 催化
  • 化學 (全部)

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