Preparation of functionalized aryl magnesium reagents by the addition of magnesium aryl thiolates and amides to arynes

Wenwei Lin*, Ioannis Sapountzis, Paul Knochel

*此作品的通信作者

研究成果: 雜誌貢獻期刊論文同行評審

79 引文 斯高帕斯(Scopus)

摘要

(Chemical Equation Presented) Reactive arynes, which are readily generated by the reaction of ortho-iocloarylsulfonates with iPrMgCl, undergo the smooth addition of various magnesium nucleophiles like magnesium thiolates, selenides, and amides. In all cases the resulting functionalized aryl magnesium species can be trapped by an electrophile leading to highly functionalized aromatic compounds (see scheme).

原文英語
頁(從 - 到)4258-4261
頁數4
期刊Angewandte Chemie - International Edition
44
發行號27
DOIs
出版狀態已發佈 - 2005 7月 4
對外發佈

ASJC Scopus subject areas

  • 催化
  • 化學 (全部)

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