摘要
We study the polarization and electrostatic interactions of an ionic system under geometric confinement in the strong-interacting regime. The geometric confinement is introduced via a simple two-ring model, where ions of each species are confined on a ring, respectively. The observed polarization curve exhibits staircase transitions in the low-temperature regime, due to the crossover between energy local minima. We examine the criterion for the validity of the linear response theory and introduce a simple two-state picture that illustrates the signatures of the crossover phenomena.
原文 | 英語 |
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文章編號 | 244904 |
期刊 | Journal of Chemical Physics |
卷 | 137 |
發行號 | 24 |
DOIs | |
出版狀態 | 已發佈 - 2012 12月 28 |
ASJC Scopus subject areas
- 一般物理與天文學
- 物理與理論化學