Photolysis and photocatalytic decomposition of sulfamethazine antibiotics in an aqueous solution with TiO 2

Tai Wei Tzeng, Shan Li Wang, C. C. Chen, Chen Chung Tan, Yu Ting Liu, Tsan Yao Chen, Yu Min Tzou*, C. C. Chen, J. T. Hung

*此作品的通信作者

研究成果: 雜誌貢獻期刊論文同行評審

37 引文 斯高帕斯(Scopus)

摘要

Photo-decomposition of sulfamethazine (SMT) involves photolytic and photo-catalytic reactions, which occur simultaneously. The relative contributions of these two reactions to the overall SMT photo-decompositions by TiO 2 and the intermediates of SMT photo-decompositions were systematically examined with the effects of TiO 2 loading, and the pH and the initial SMT concentrations in the solutions. The apparent rate constants of SMT photo-decomposition reactions, which were well described by the pseudo-first-order kinetic model, ranged from 0.24 to 1.61 h -1 . The overall photo-decomposition efficiencies of 0.072 mM SMT were the highest at pH 5.5 with 0.5 g L -1 TiO 2 due to the adsorption-induced photocatalytic decomposition of SMT on TiO 2 . However, the SMT photolysis occurred more rapidly at pH 10. Two reactive species of holes and hydroxyl radicals concurrently participated in the photocatalytic decomposition of SMT, and the latter dominated the oxidative reactions of SMT on TiO 2 . Eight intermediates of SMT photo-decomposition were determined using LC-MS. Their time-dependent distributions indicated that the photo-decomposition of SMT was triggered by hydroxylation on aniline and dimethylpyrimidinyl moieties, followed by the cleavage of the S-N bond of SMT. Our results illustrated that the intermediates with dimethylpyrimidinyl groups possess strong resistance to photo-decomposition and played a determinant role in the photo-decomposition of SMT.

原文英語
頁(從 - 到)69301-69310
頁數10
期刊RSC Advances
6
發行號73
DOIs
出版狀態已發佈 - 2016 一月 1

ASJC Scopus subject areas

  • 化學 (全部)
  • 化學工程 (全部)

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