Photoelectrochemistry and interfacial energetics of titanium dioxide photoelectrodes in fluoride-containing solutions

Mou Wang Chong, Thomas E. Mallouk

研究成果: 雜誌貢獻文章

27 引文 斯高帕斯(Scopus)

摘要

In a preliminary report, the authors described the photoelectrochemical production of fluorine from anhydrous hydrogen fluoride solutions using single-crystal TiO2 electrodes. It was found that fluorine doping substantially enhanced the stability of n-TiO2 photoelectrodes in HF/NaF. They now report a fuller characterization of these effects and a study of the energetics of the semiconductor/fluoride-containing solution interface by ac impedance techniques. This study reveals an extremely low density of midgap surface states, which allows the electrode to develop a large open circuit photovoltage and to evolve fluorine efficiently, and without substantial photoanodic corrosion, from anhydrous hydrogen fluoride solutions. This same low density of surface states, and a shift of the valence band-edge to more negative potentials, gives rise to a complete lack of photoactivity in fluoride-containing acetonitrile solutions.

原文英語
頁(從 - 到)423-428
頁數6
期刊Journal of physical chemistry
94
發行號1
DOIs
出版狀態已發佈 - 1990 一月 1

    指紋

ASJC Scopus subject areas

  • Engineering(all)
  • Physical and Theoretical Chemistry

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