Photocatalytic oxidation of bromide to bromine

Kelvin Yun Da Tsai, I. Jy Chang

研究成果: 雜誌貢獻期刊論文同行評審

11 引文 斯高帕斯(Scopus)

摘要

Three consecutive bimolecular reactions are employed to photocatalyze bromide oxidation to bromine. The system consists of a ruthenium(II) complex, [Ru(deeb)2(dmbpy)]2+ (deeb = 4,4'-diethylester-2,2'-bipyridine; dmbpy = 4,4'-dimethyl-2,2'-bipyridine), 4-bromobenzenediazonium tetrafluoroborate (ArN2BF4), and Br-. Varying reagent concentrations allowed us to optimize the sequence of reactions for product formation. The electronically excited ruthenium complex (Ru) reacts first with ArN2BF4 to produce a ruthenium(III) (RuIII) intermediate, triggering a subsequent reaction with Br-. Transient absorption measured at 486 and 380 nm provides insight into the time-dependent concentrations of Ru, RuIII, and Br2•- Without interference of backelectron transfer, the rate constant for an equal concentration bimolecular reaction of Br2•- was determined to be 5 × 109 M-1 s-1. The final products, bromine and tribromide, were spectroscopically characterized, and the turnover number (TON) was 230.

原文英語
頁(從 - 到)693-696
頁數4
期刊Inorganic Chemistry
56
發行號2
DOIs
出版狀態已發佈 - 2017 一月 17

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Inorganic Chemistry

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