Oxidation of Tricarbonyl (η1 η2‐but‐3‐en‐1‐yl)iron(0)and Tricarbonyl (η3‐allyl)iron(0) Anion Complexes with Dioxygen

Chong‐Chen ‐C Hwu; Ming‐Chang P. Yeh

doi:10.1002/jccs.199500112

Oxidation of Tricarbonyl (η¹ η²‐but‐3‐en‐1‐yl)iron(0)and Tricarbonyl (η³‐allyl)iron(0) Anion Complexes with Dioxygen

Chong‐Chen ‐C Hwu^*, Ming‐Chang P. Yeh

^*此作品的通信作者

化學系

研究成果: 雜誌貢獻 › 期刊論文 › 同行評審

2 引文斯高帕斯（Scopus）

摘要

The addition of reactive carbanions to tricarbonyl(η⁴‐1,3‐diene)iron(0) complexes proceeded at −78 °C to give putative tricarbonyl(η¹,η²‐but‐3‐en‐1‐y1)iron(0) anion complexes and at 25 °C to produce postulated tricarbonyl(η³‐allyl)iron(O) anion complexes; trapping of reactive intermediates with dioxygen produced γ,δ‐unsaturated acids and allylic alcohols, respectively.

原文	英語
頁（從 - 到）	825-831
頁數	7
期刊	Journal of the Chinese Chemical Society
卷	42
發行號	5
DOIs	https://doi.org/10.1002/jccs.199500112
出版狀態	已發佈 - 1995 10月

ASJC Scopus subject areas

一般化學

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10.1002/jccs.199500112

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title = "Oxidation of Tricarbonyl (η1 η2‐but‐3‐en‐1‐yl)iron(0)and Tricarbonyl (η3‐allyl)iron(0) Anion Complexes with Dioxygen",

abstract = "The addition of reactive carbanions to tricarbonyl(η4‐1,3‐diene)iron(0) complexes proceeded at −78 °C to give putative tricarbonyl(η1,η2‐but‐3‐en‐1‐y1)iron(0) anion complexes and at 25 °C to produce postulated tricarbonyl(η3‐allyl)iron(O) anion complexes; trapping of reactive intermediates with dioxygen produced γ,δ‐unsaturated acids and allylic alcohols, respectively.",

keywords = "Allylic alcohols, Diene iron complex, γ,δ‐Unsaturated acids",

author = "Hwu, {Chong‐Chen ‐C} and Yeh, {Ming‐Chang P.}",

year = "1995",

month = oct,

doi = "10.1002/jccs.199500112",

language = "English",

volume = "42",

pages = "825--831",

journal = "Journal of the Chinese Chemical Society",

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publisher = "John Wiley and Sons Inc.",

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TY - JOUR

T1 - Oxidation of Tricarbonyl (η1 η2‐but‐3‐en‐1‐yl)iron(0)and Tricarbonyl (η3‐allyl)iron(0) Anion Complexes with Dioxygen

AU - Hwu, Chong‐Chen ‐C

AU - Yeh, Ming‐Chang P.

PY - 1995/10

Y1 - 1995/10

N2 - The addition of reactive carbanions to tricarbonyl(η4‐1,3‐diene)iron(0) complexes proceeded at −78 °C to give putative tricarbonyl(η1,η2‐but‐3‐en‐1‐y1)iron(0) anion complexes and at 25 °C to produce postulated tricarbonyl(η3‐allyl)iron(O) anion complexes; trapping of reactive intermediates with dioxygen produced γ,δ‐unsaturated acids and allylic alcohols, respectively.

AB - The addition of reactive carbanions to tricarbonyl(η4‐1,3‐diene)iron(0) complexes proceeded at −78 °C to give putative tricarbonyl(η1,η2‐but‐3‐en‐1‐y1)iron(0) anion complexes and at 25 °C to produce postulated tricarbonyl(η3‐allyl)iron(O) anion complexes; trapping of reactive intermediates with dioxygen produced γ,δ‐unsaturated acids and allylic alcohols, respectively.

KW - Allylic alcohols

KW - Diene iron complex

KW - γ,δ‐Unsaturated acids

UR - http://www.scopus.com/inward/record.url?scp=84986516486&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=84986516486&partnerID=8YFLogxK

U2 - 10.1002/jccs.199500112

DO - 10.1002/jccs.199500112

M3 - Article

AN - SCOPUS:84986516486

SN - 0009-4536

VL - 42

SP - 825

EP - 831

JO - Journal of the Chinese Chemical Society

JF - Journal of the Chinese Chemical Society

IS - 5

ER -

Oxidation of Tricarbonyl (η1 η2‐but‐3‐en‐1‐yl)iron(0)and Tricarbonyl (η3‐allyl)iron(0) Anion Complexes with Dioxygen

摘要

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Oxidation of Tricarbonyl (η¹ η²‐but‐3‐en‐1‐yl)iron(0)and Tricarbonyl (η³‐allyl)iron(0) Anion Complexes with Dioxygen