Origin of metal-insulator transition in the weak-ferromagnetic superconductor system RuSr2RCu2O8 (R = rare earths)

B. C. Chang*, C. Y. Yang, Y. Y. Hsu, H. C. Ku


研究成果: 雜誌貢獻期刊論文同行評審


For the oxygen-annealed weak-ferromagnetic superconductor system RuSr2RCu2O8 (R = rare earths), superconducting transition temperature Tsc decreases steadily from maximum 56 K for smaller rare earth Gd3+ (ionic radius r = 0.105 nm), to 54 K for (Eu0.5Gd0.5)3+, 36 K for Eu3+, 8 K for (Sm0.5Eu0.5)3+, and metallic but not superconducting for larger Sm3+ (r = 0.108 nm), with a metal-insulator transition for even larger rare earth ions Nd3+ (r = 0.112 nm) and Pr3+ (r = 0.113 nm). Powder X-ray diffraction Rietveld refinement study indicates that the insulating phase is stabilized in the undistorted tetragonal phase (space group P4/mmm) with the larger tetragonal lattice parameter a ∼ 0.390-392 nm, which gives a reasonable Ru5+-O bond length of d ∼ 0.197 nm. On the other hand, the metallic phase with smaller rare earth ions can be stabilized only in the distorted tetragonal phase (space group P4/mbm), with the smaller a/√2 ∼ 0.383-0.385 nm but still provide a reasonable Ru-O bond length through RuO6 octahedron rotation. The metal-insulator transition as well as the variation of superconducting Tsc is closely related to oxygen deficiency content δ which control the variation of mobile hole concentration and structural variation in this hole-doped superconductor system.

頁(從 - 到)503-505
期刊Physica C: Superconductivity and its applications
460-462 I
出版狀態已發佈 - 2007 九月 1

ASJC Scopus subject areas

  • 電子、光磁材料
  • 凝聚態物理學
  • 能源工程與電力技術
  • 電氣與電子工程


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