摘要
Adding value: The direct vinylogous Michael addition of γ-substituted butenolides with a series of 3-aroyl acrylates and 1,2-diaroylethylenes has been demonstrated. This organocatalytic method delivers highly enantio- and diastereomerically pure γ,γ-disubstituted butenolides with adjacent quaternary and tertiary stereocenters (see scheme).
| 原文 | 英語 |
|---|---|
| 頁（從 - 到） | 7713-7717 |
| 頁數 | 5 |
| 期刊 | Chemistry - A European Journal |
| 卷 | 19 |
| 發行號 | 24 |
| DOIs | |
| 出版狀態 | 已發佈 - 2013 6月 10 |
ASJC Scopus subject areas
- 催化
- 有機化學
指紋
深入研究「Organocatalytic enantioselective direct vinylogous michael addition of γ-substituted butenolides to 3-aroyl acrylates and 1,2-diaroylethylenes」主題。共同形成了獨特的指紋。資料集
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CCDC 931121: Experimental Crystal Structure Determination
Das, U. (Creator), Chen, Y. (Creator), Tsai, Y. (Creator) & Lin, W. (Creator), Unknown Publisher, 2013
DOI: 10.5517/cc107x5b, http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/cc107x5b&sid=DataCite
資料集: Dataset
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CCDC 931120: Experimental Crystal Structure Determination
Das, U. (Creator), Chen, Y. (Creator), Tsai, Y. (Creator) & Lin, W. (Creator), Unknown Publisher, 2013
DOI: 10.5517/cc107x49, http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/cc107x49&sid=DataCite
資料集: Dataset