Nucleophilic Reactivity of Zinc and Copper Carbenoids. 2

Paul Knochel; Tso sheng Chou; Huai Gu Chen; Ming Chang P. Yeh; Michael J. Rozema

doi:10.1021/jo00283a006

Nucleophilic Reactivity of Zinc and Copper Carbenoids. 2

Paul Knochel^*, Tso sheng Chou, Huai Gu Chen, Ming Chang P. Yeh, Michael J. Rozema

^*此作品的通信作者

研究成果: 雜誌貢獻 › 期刊論文 › 同行評審

78 引文斯高帕斯（Scopus）

摘要

: The reactivity of the new zinc and copper carbenoids PivOCH₂Cu(CN)ZnI (4) and ICH₂Cu·ZnI₂(5) toward various electrophiles has been investigated. of special interest is the direct and highly stereoselective conversion of allylic bromides to the corresponding homoallylic iodides by using the reagent ICH₂Cu·ZnI₂(5).

原文	英語
頁（從 - 到）	5202-5204
頁數	3
期刊	Journal of Organic Chemistry
卷	54
發行號	22
DOIs	https://doi.org/10.1021/jo00283a006
出版狀態	已發佈 - 1989 10月 1
對外發佈	是

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有機化學

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10.1021/jo00283a006

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title = "Nucleophilic Reactivity of Zinc and Copper Carbenoids. 2",

abstract = ": The reactivity of the new zinc and copper carbenoids PivOCH2Cu(CN)ZnI (4) and ICH2Cu·ZnI2(5) toward various electrophiles has been investigated. of special interest is the direct and highly stereoselective conversion of allylic bromides to the corresponding homoallylic iodides by using the reagent ICH2Cu·ZnI2(5).",

author = "Paul Knochel and Chou, {Tso sheng} and Chen, {Huai Gu} and Yeh, {Ming Chang P.} and Rozema, {Michael J.}",

year = "1989",

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doi = "10.1021/jo00283a006",

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AU - Knochel, Paul

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AU - Yeh, Ming Chang P.

AU - Rozema, Michael J.

PY - 1989/10/1

Y1 - 1989/10/1

N2 - : The reactivity of the new zinc and copper carbenoids PivOCH2Cu(CN)ZnI (4) and ICH2Cu·ZnI2(5) toward various electrophiles has been investigated. of special interest is the direct and highly stereoselective conversion of allylic bromides to the corresponding homoallylic iodides by using the reagent ICH2Cu·ZnI2(5).

AB - : The reactivity of the new zinc and copper carbenoids PivOCH2Cu(CN)ZnI (4) and ICH2Cu·ZnI2(5) toward various electrophiles has been investigated. of special interest is the direct and highly stereoselective conversion of allylic bromides to the corresponding homoallylic iodides by using the reagent ICH2Cu·ZnI2(5).

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Nucleophilic Reactivity of Zinc and Copper Carbenoids. 2

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