Nucleophilic Reactivity of Zinc and Copper Carbenoids. 2

Paul Knochel*, Tso sheng Chou, Huai Gu Chen, Ming-Chang P. Yeh, Michael J. Rozema

*此作品的通信作者

研究成果: 雜誌貢獻期刊論文同行評審

76 引文 斯高帕斯(Scopus)

摘要

: The reactivity of the new zinc and copper carbenoids PivOCH2Cu(CN)ZnI (4) and ICH2Cu·ZnI2(5) toward various electrophiles has been investigated. of special interest is the direct and highly stereoselective conversion of allylic bromides to the corresponding homoallylic iodides by using the reagent ICH2Cu·ZnI2(5).

原文英語
頁(從 - 到)5202-5204
頁數3
期刊Journal of Organic Chemistry
54
發行號22
DOIs
出版狀態已發佈 - 1989 十月 1
對外發佈

ASJC Scopus subject areas

  • 有機化學

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