Nucleophilic Addition to (η3‐Allyl)Fe(CO)4 Cations with Functionalized Zinc‐Copper Reagents RCu(Znl)CN

Sen‐I ‐I Tau, Ming‐Chang P. Yeh

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2 引文 斯高帕斯(Scopus)

摘要

Regioselectivity of the addition of the highly functionalized zinc‐copper reagents to (η3‐allyl)Fe(CO)4 cationic salts was studied. For 1,1‐disubstituted allyl cation 1, the zinc‐copper reagents added predominantly at the unsubstituted terminus. For 1,1,2‐trisubstituted allyl cation 2, reactive zinc‐copper reagents attacked mainly at the unsubstituted terminus while less reactive zinc‐copper reagents added to a coordinated CO ligand. For 1,1,3‐trisubstituted allyl cation 3, the addition occurred at both the less substituted allyl terminus and a coordinated CO ligand.

原文英語
頁(從 - 到)401-408
頁數8
期刊Journal of the Chinese Chemical Society
39
發行號5
DOIs
出版狀態已發佈 - 1992 十月

ASJC Scopus subject areas

  • Chemistry(all)

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