Multielectron photochemistry of quadruply bonded metal-metal complexes

Colleen M. Partigianoni*, I. Jy Chang, Daniel G. Nocera

*此作品的通信作者

研究成果: 雜誌貢獻期刊論文同行評審

15 引文 斯高帕斯(Scopus)

摘要

The structural, electronic, and oxidation-reduction properties of multiply bonded metal-metal ({A figure is presented}) dimers presage a rich excited state chemistry for these complexes. Our work has emphasized photochemical pathways that utilize ({A figure is presented}) dimers to promote overall multielectron transformations. Multielectron photochemistry can only be achieved by correctly manipulating the molecular and electronic structures of these dimers such that one-electron pathways are circumvented. We now present a summary of the strategy used for the rational design of ({A figure is presented}) multielectron photochemical schemes.

原文英語
頁(從 - 到)105-117
頁數13
期刊Coordination Chemistry Reviews
97
發行號C
DOIs
出版狀態已發佈 - 1990 一月
對外發佈

ASJC Scopus subject areas

  • 物理與理論化學
  • 無機化學
  • 材料化學

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