Morita–Baylis–Hillman (MBH) Reaction Derived Nitroallylic Alcohols, Acetates and Amines as Synthons in Organocatalysis and Heterocycle Synthesis

Wan Yun Huang, Shaik Anwar, Kwunmin Chen*

*此作品的通信作者

研究成果: 雜誌貢獻回顧評介論文同行評審

26 引文 斯高帕斯(Scopus)

摘要

The Morita–Baylis–Hillman (MBH) reaction is one of the most useful and efficient protocols for constructing new carbon–carbon bonds between an activated olefin and electrophiles in the presence of a tertiary amine/phosphine. Herein, we present the use of MBH alcohols, which are obtained from the reaction of nitrostyrenes with aldehydes, as well as acetates and amines derived thereof in several organocatalytic transformations. Densely functionalised MBH adducts can also be used to synthesise substituted heteroaromatic compounds, such as furan, pyrrole, pyrazole and imidazole derivatives.

原文英語
頁(從 - 到)363-381
頁數19
期刊Chemical Record
17
發行號3
DOIs
出版狀態已發佈 - 2017 三月 1

ASJC Scopus subject areas

  • 化學 (全部)
  • 生物化學
  • 化學工程 (全部)
  • 材料化學

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