Molybdenum-mediated diastereoselective synthesis of 2-heterobicyclo[4.4.0]decene derivatives

Ming Chang P. Yeh; Chong Nan Chaung

doi:10.1039/p19960002167

Molybdenum-mediated diastereoselective synthesis of 2-heterobicyclo[4.4.0]decene derivatives

Ming Chang P. Yeh^*
, Chong Nan Chaung

^*此作品的通信作者

化學系

研究成果: 雜誌貢獻 › 期刊論文 › 同行評審

10 引文斯高帕斯（Scopus）

摘要

The addition of a variety of functionalized zinc-copper reagents RCu(CN)ZnI 2 to (η⁵-cyclopentadienyl)(η ⁴-cyclohexa-1,3-diene)dicarbonylmolybdenum cation 1 proceeds in a highly regio- and stereo-specific fashion to generate (η⁵-cyclopentadienyl)(π-allyl)dicarbonylmolybdenum complexes 3 with a functionalized side-chain at the C-4 position of the ring. Intramolecular cyclization of the (π-allyl)molybdenum complexes containing a pendant alcohol, carboxylic acid, thiol or amine functionality affords fused 2-heterobicyclo[4.4.0]decene derivatives.

原文	英語
頁（從 - 到）	2167-2172
頁數	6
期刊	Journal of the Chemical Society - Perkin Transactions 1
發行號	17
DOIs	https://doi.org/10.1039/p19960002167
出版狀態	已發佈 - 1996 9月 7

ASJC Scopus subject areas

一般化學

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10.1039/p19960002167

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title = "Molybdenum-mediated diastereoselective synthesis of 2-heterobicyclo[4.4.0]decene derivatives",

abstract = "The addition of a variety of functionalized zinc-copper reagents RCu(CN)ZnI 2 to (η5-cyclopentadienyl)(η 4-cyclohexa-1,3-diene)dicarbonylmolybdenum cation 1 proceeds in a highly regio- and stereo-specific fashion to generate (η5-cyclopentadienyl)(π-allyl)dicarbonylmolybdenum complexes 3 with a functionalized side-chain at the C-4 position of the ring. Intramolecular cyclization of the (π-allyl)molybdenum complexes containing a pendant alcohol, carboxylic acid, thiol or amine functionality affords fused 2-heterobicyclo[4.4.0]decene derivatives.",

author = "Yeh, \{Ming Chang P.\} and Chaung, \{Chong Nan\}",

year = "1996",

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AU - Chaung, Chong Nan

PY - 1996/9/7

Y1 - 1996/9/7

N2 - The addition of a variety of functionalized zinc-copper reagents RCu(CN)ZnI 2 to (η5-cyclopentadienyl)(η 4-cyclohexa-1,3-diene)dicarbonylmolybdenum cation 1 proceeds in a highly regio- and stereo-specific fashion to generate (η5-cyclopentadienyl)(π-allyl)dicarbonylmolybdenum complexes 3 with a functionalized side-chain at the C-4 position of the ring. Intramolecular cyclization of the (π-allyl)molybdenum complexes containing a pendant alcohol, carboxylic acid, thiol or amine functionality affords fused 2-heterobicyclo[4.4.0]decene derivatives.

AB - The addition of a variety of functionalized zinc-copper reagents RCu(CN)ZnI 2 to (η5-cyclopentadienyl)(η 4-cyclohexa-1,3-diene)dicarbonylmolybdenum cation 1 proceeds in a highly regio- and stereo-specific fashion to generate (η5-cyclopentadienyl)(π-allyl)dicarbonylmolybdenum complexes 3 with a functionalized side-chain at the C-4 position of the ring. Intramolecular cyclization of the (π-allyl)molybdenum complexes containing a pendant alcohol, carboxylic acid, thiol or amine functionality affords fused 2-heterobicyclo[4.4.0]decene derivatives.

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DO - 10.1039/p19960002167

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JO - Journal of the Chemical Society - Perkin Transactions 1

JF - Journal of the Chemical Society - Perkin Transactions 1

IS - 17

ER -

Molybdenum-mediated diastereoselective synthesis of 2-heterobicyclo[4.4.0]decene derivatives

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