TY - JOUR
T1 - Metal-organic frameworks to metal/metal oxide embedded carbon matrix
T2 - Synthesis, characterization and gas sorption properties
AU - Chen, Jiun Jen
AU - Chen, Ya Ting
AU - Raja, Duraisamy Senthil
AU - Kang, Yu Hao
AU - Tseng, Pen Chang
AU - Lin, Chia Her
N1 - Publisher Copyright:
© 2015 by the authors.
PY - 2015
Y1 - 2015
N2 - Three isostructural metal-organic frameworks, (MOFs), [Fe(OH)(1,4-NDC)] (1), [Al(OH)(1,4-NDC)] (2), and [In(OH)(1,4-NDC)] (3) have been synthesized hydrothermally by using 1,4-naphthalene dicarboxylate (1,4-NDC) as a linker. The MOFs were characterized using various techniques and further used as precursor materials for the synthesis of metal/metal oxide nanoparticles inserted in a carbon matrix through a simple thermal conversion method. The newly synthesized carbon materials were characterized by scanning electron microscopy, transmission electron microscopy, energy-dispersive X-ray spectroscopy analysis, powder X-ray diffraction and BET analysis. The results showed that the MOF-derived carbon composite materials maintained the morphology of the original MOF upon carbonization, and confirmed the insertion of metal/metal oxide particles in the carbon matrix.
AB - Three isostructural metal-organic frameworks, (MOFs), [Fe(OH)(1,4-NDC)] (1), [Al(OH)(1,4-NDC)] (2), and [In(OH)(1,4-NDC)] (3) have been synthesized hydrothermally by using 1,4-naphthalene dicarboxylate (1,4-NDC) as a linker. The MOFs were characterized using various techniques and further used as precursor materials for the synthesis of metal/metal oxide nanoparticles inserted in a carbon matrix through a simple thermal conversion method. The newly synthesized carbon materials were characterized by scanning electron microscopy, transmission electron microscopy, energy-dispersive X-ray spectroscopy analysis, powder X-ray diffraction and BET analysis. The results showed that the MOF-derived carbon composite materials maintained the morphology of the original MOF upon carbonization, and confirmed the insertion of metal/metal oxide particles in the carbon matrix.
KW - 1,4-naphthalene dicarboxylate
KW - Gas sorption
KW - Metal oxide nanoparticle
KW - Metal-organic frameworks
KW - Nanoporous carbon
UR - https://www.scopus.com/pages/publications/84940034330
UR - https://www.scopus.com/pages/publications/84940034330#tab=citedBy
U2 - 10.3390/ma8085245
DO - 10.3390/ma8085245
M3 - Article
AN - SCOPUS:84940034330
SN - 1996-1944
VL - 8
SP - 5336
EP - 5347
JO - Materials
JF - Materials
IS - 8
ER -