摘要
High oxygen pressure annealed PrBa2Cu3O7-y (y∼0) cuprates were prepared in order to study the effect of oxygen stoichiometric parameter y on the unusual Pr/Cu magnetic properties and/or recently reported superconductivity. The oxygen-rich orthorhombic 123-chain phase is highly unstable under high-oxygen pressure synthesis and decomposes completely in 10 bar pressure. For a smaller 2 bar prepared sample a relatively clean phase was preserved with an oxygen parameter y = 0.05, as compared with y = 0.11 from a conventional 1 bar flowing oxygen method. No superconductivity can be detected for all high-oxygen pressure prepared samples. Instead, Mott-insulator behavior with anomalous high Pr ordering TN(Pr) = 19 K was observed for PrBa2Cu3O6.95. Comparison with other Pr/Ba intersubstituted Pr1-xBa2-xCu3O7-y cuprates is discussed.
原文 | 英語 |
---|---|
頁(從 - 到) | 7484-7486 |
頁數 | 3 |
期刊 | Journal of Applied Physics |
卷 | 89 |
發行號 | 11 II |
DOIs | |
出版狀態 | 已發佈 - 2001 6月 1 |
對外發佈 | 是 |
事件 | 8th Joint Magnetism and Magnetic Materials-Intermag Conference - San Antonio, TX, 美国 持續時間: 2001 1月 7 → 2001 1月 11 |
ASJC Scopus subject areas
- 一般物理與天文學