Luminescence enhancement induced by aggregation of alkoxy-bridged rhenium(I) molecular rectangles

Bala Manimaran; P. Thanasekaran; T. Rajendran; Ren Jay Lin; I. Jy Chang; Gene Hsiang Lee; Shie Ming Peng; S. Rajagopal; Kuang Lieh Lu

doi:10.1021/ic020364n

Luminescence enhancement induced by aggregation of alkoxy-bridged rhenium(I) molecular rectangles

Bala Manimaran, P. Thanasekaran, T. Rajendran, Ren Jay Lin, I. Jy Chang, Gene Hsiang Lee, Shie Ming Peng, S. Rajagopal, Kuang Lieh Lu^*

^*此作品的通信作者

化學系

研究成果: 雜誌貢獻 › 期刊論文 › 同行評審

95 引文斯高帕斯（Scopus）

摘要

Self-assembly of rhenium(I)-based molecular rectangles containing long alkyl chains has been achieved in one-pot synthesis by solvothermal methods. An enormous enhancement in the emission intensity, quantum yield, and lifetime of the rectangles has been observed when the solvent medium is changed from organic to aqueous. Addition of water favors the aggregation of Re(I) molecular rectangle resulting in the luminescence enhancement, and this phenomenon has been traced out using light scattering techniques.

原文	英語
頁（從 - 到）	5323-5325
頁數	3
期刊	Inorganic Chemistry
卷	41
發行號	21
DOIs	https://doi.org/10.1021/ic020364n
出版狀態	已發佈 - 2002 十月 21

ASJC Scopus subject areas

物理與理論化學
無機化學

存取文件

10.1021/ic020364n

其它文件與鏈接

引用此

Luminescence enhancement induced by aggregation of alkoxy-bridged rhenium(I) molecular rectangles. / Manimaran, Bala; Thanasekaran, P.; Rajendran, T.; Lin, Ren Jay; Chang, I. Jy; Lee, Gene Hsiang; Peng, Shie Ming; Rajagopal, S.; Lu, Kuang Lieh.

於: Inorganic Chemistry, 卷 41, 編號 21, 21.10.2002, p. 5323-5325.

研究成果: 雜誌貢獻 › 期刊論文 › 同行評審

@article{5b719c82329d414a82119586c43f2bb5,

title = "Luminescence enhancement induced by aggregation of alkoxy-bridged rhenium(I) molecular rectangles",

abstract = "Self-assembly of rhenium(I)-based molecular rectangles containing long alkyl chains has been achieved in one-pot synthesis by solvothermal methods. An enormous enhancement in the emission intensity, quantum yield, and lifetime of the rectangles has been observed when the solvent medium is changed from organic to aqueous. Addition of water favors the aggregation of Re(I) molecular rectangle resulting in the luminescence enhancement, and this phenomenon has been traced out using light scattering techniques.",

author = "Bala Manimaran and P. Thanasekaran and T. Rajendran and Lin, {Ren Jay} and Chang, {I. Jy} and Lee, {Gene Hsiang} and Peng, {Shie Ming} and S. Rajagopal and Lu, {Kuang Lieh}",

year = "2002",

month = oct,

day = "21",

doi = "10.1021/ic020364n",

language = "English",

volume = "41",

pages = "5323--5325",

journal = "Inorganic Chemistry",

issn = "0020-1669",

publisher = "American Chemical Society",

number = "21",

}

TY - JOUR

T1 - Luminescence enhancement induced by aggregation of alkoxy-bridged rhenium(I) molecular rectangles

AU - Manimaran, Bala

AU - Thanasekaran, P.

AU - Rajendran, T.

AU - Lin, Ren Jay

AU - Chang, I. Jy

AU - Lee, Gene Hsiang

AU - Peng, Shie Ming

AU - Rajagopal, S.

AU - Lu, Kuang Lieh

PY - 2002/10/21

Y1 - 2002/10/21

N2 - Self-assembly of rhenium(I)-based molecular rectangles containing long alkyl chains has been achieved in one-pot synthesis by solvothermal methods. An enormous enhancement in the emission intensity, quantum yield, and lifetime of the rectangles has been observed when the solvent medium is changed from organic to aqueous. Addition of water favors the aggregation of Re(I) molecular rectangle resulting in the luminescence enhancement, and this phenomenon has been traced out using light scattering techniques.

AB - Self-assembly of rhenium(I)-based molecular rectangles containing long alkyl chains has been achieved in one-pot synthesis by solvothermal methods. An enormous enhancement in the emission intensity, quantum yield, and lifetime of the rectangles has been observed when the solvent medium is changed from organic to aqueous. Addition of water favors the aggregation of Re(I) molecular rectangle resulting in the luminescence enhancement, and this phenomenon has been traced out using light scattering techniques.

UR - http://www.scopus.com/inward/record.url?scp=0037152375&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=0037152375&partnerID=8YFLogxK

U2 - 10.1021/ic020364n

DO - 10.1021/ic020364n

M3 - Article

C2 - 12377024

AN - SCOPUS:0037152375

VL - 41

SP - 5323

EP - 5325

JO - Inorganic Chemistry

JF - Inorganic Chemistry

SN - 0020-1669

IS - 21

ER -

Luminescence enhancement induced by aggregation of alkoxy-bridged rhenium(I) molecular rectangles

摘要

ASJC Scopus subject areas

存取文件

其它文件與鏈接

指紋

引用此