Luminescence enhancement induced by aggregation of alkoxy-bridged rhenium(I) molecular rectangles

Bala Manimaran; P. Thanasekaran; T. Rajendran; Ren Jay Lin; I. Jy Chang; Gene Hsiang Lee; Shie Ming Peng; S. Rajagopal; Kuang Lieh Lu

doi:10.1021/ic020364n

Luminescence enhancement induced by aggregation of alkoxy-bridged rhenium(I) molecular rectangles

Bala Manimaran, P. Thanasekaran, T. Rajendran, Ren Jay Lin, I. Jy Chang, Gene Hsiang Lee, Shie Ming Peng, S. Rajagopal, Kuang Lieh Lu^*

^*此作品的通信作者

化學系

研究成果: 雜誌貢獻 › 期刊論文 › 同行評審

99 引文斯高帕斯（Scopus）

摘要

Self-assembly of rhenium(I)-based molecular rectangles containing long alkyl chains has been achieved in one-pot synthesis by solvothermal methods. An enormous enhancement in the emission intensity, quantum yield, and lifetime of the rectangles has been observed when the solvent medium is changed from organic to aqueous. Addition of water favors the aggregation of Re(I) molecular rectangle resulting in the luminescence enhancement, and this phenomenon has been traced out using light scattering techniques.

原文	英語
頁（從 - 到）	5323-5325
頁數	3
期刊	Inorganic Chemistry
卷	41
發行號	21
DOIs	https://doi.org/10.1021/ic020364n
出版狀態	已發佈 - 2002 10月 21

ASJC Scopus subject areas

物理與理論化學
無機化學

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10.1021/ic020364n

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abstract = "Self-assembly of rhenium(I)-based molecular rectangles containing long alkyl chains has been achieved in one-pot synthesis by solvothermal methods. An enormous enhancement in the emission intensity, quantum yield, and lifetime of the rectangles has been observed when the solvent medium is changed from organic to aqueous. Addition of water favors the aggregation of Re(I) molecular rectangle resulting in the luminescence enhancement, and this phenomenon has been traced out using light scattering techniques.",

author = "Bala Manimaran and P. Thanasekaran and T. Rajendran and Lin, {Ren Jay} and Chang, {I. Jy} and Lee, {Gene Hsiang} and Peng, {Shie Ming} and S. Rajagopal and Lu, {Kuang Lieh}",

year = "2002",

month = oct,

day = "21",

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T1 - Luminescence enhancement induced by aggregation of alkoxy-bridged rhenium(I) molecular rectangles

AU - Manimaran, Bala

AU - Thanasekaran, P.

AU - Rajendran, T.

AU - Lin, Ren Jay

AU - Chang, I. Jy

AU - Lee, Gene Hsiang

AU - Peng, Shie Ming

AU - Rajagopal, S.

AU - Lu, Kuang Lieh

PY - 2002/10/21

Y1 - 2002/10/21

N2 - Self-assembly of rhenium(I)-based molecular rectangles containing long alkyl chains has been achieved in one-pot synthesis by solvothermal methods. An enormous enhancement in the emission intensity, quantum yield, and lifetime of the rectangles has been observed when the solvent medium is changed from organic to aqueous. Addition of water favors the aggregation of Re(I) molecular rectangle resulting in the luminescence enhancement, and this phenomenon has been traced out using light scattering techniques.

AB - Self-assembly of rhenium(I)-based molecular rectangles containing long alkyl chains has been achieved in one-pot synthesis by solvothermal methods. An enormous enhancement in the emission intensity, quantum yield, and lifetime of the rectangles has been observed when the solvent medium is changed from organic to aqueous. Addition of water favors the aggregation of Re(I) molecular rectangle resulting in the luminescence enhancement, and this phenomenon has been traced out using light scattering techniques.

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JO - Inorganic Chemistry

JF - Inorganic Chemistry

SN - 0020-1669

IS - 21

ER -

Luminescence enhancement induced by aggregation of alkoxy-bridged rhenium(I) molecular rectangles

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