Luminescence enhancement induced by aggregation of alkoxy-bridged rhenium(I) molecular rectangles

Bala Manimaran, P. Thanasekaran, T. Rajendran, Ren Jay Lin, I. Jy Chang, Gene Hsiang Lee, Shie Ming Peng, S. Rajagopal, Kuang Lieh Lu

研究成果: 雜誌貢獻文章

88 引文 斯高帕斯(Scopus)

摘要

Self-assembly of rhenium(I)-based molecular rectangles containing long alkyl chains has been achieved in one-pot synthesis by solvothermal methods. An enormous enhancement in the emission intensity, quantum yield, and lifetime of the rectangles has been observed when the solvent medium is changed from organic to aqueous. Addition of water favors the aggregation of Re(I) molecular rectangle resulting in the luminescence enhancement, and this phenomenon has been traced out using light scattering techniques.

原文英語
頁(從 - 到)5323-5325
頁數3
期刊Inorganic Chemistry
41
發行號21
DOIs
出版狀態已發佈 - 2002 十月 21

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Inorganic Chemistry

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    Manimaran, B., Thanasekaran, P., Rajendran, T., Lin, R. J., Chang, I. J., Lee, G. H., Peng, S. M., Rajagopal, S., & Lu, K. L. (2002). Luminescence enhancement induced by aggregation of alkoxy-bridged rhenium(I) molecular rectangles. Inorganic Chemistry, 41(21), 5323-5325. https://doi.org/10.1021/ic020364n