Ligand-controlled nuclearity in nickel bis(benzimidazolyl) complexes

Way Zen Lee*, Huan Sheng Tseng, Ting Shen Kuo

*此作品的通信作者

研究成果: 雜誌貢獻期刊論文同行評審

15 引文 斯高帕斯(Scopus)

摘要

A series of nickel complexes supported with a tripodal ligand bis(1-methylbenzimidazolyl-2-methyl)amine (L) or bis(1-methylbenzimidazolyl-2-methyl)-10-camphorsulfonamide (L′) on a Ni(ii) ion were synthesized and fully characterized. The complexes, [LNiCl(µ-Cl)]2·4CH3OH (1), [LNi(CH3CN)3](ClO4)2·2CH3CN (3), and [L2Ni2(µ-OAc)3]X (X = Cl (5) or ClO4 (7)), coordinated with the tridentate L ligand, all possess an octahedral structure at the nickel center; in contrast, the geometry of the complexes, L′NiCl2 (2), [L′Ni(CH3CN)3](ClO4)2·2CH3CN (4), and L′Ni(OAc)2·0.5Et2O (6), employing the L′ ligand are either tetrahedral or octahedral. Due to the weak coordinating ability of the sulfonamide group and the steric hindrance of the camphorsulfonyl group of L′, the tripodal L′ becomes a bidentate ligand in the presence of chloride or acetate groups, which have a stronger electron donating ability than acetonitrile, bound to the nickel center. It is noteworthy that the nuclearity of the nickel complexes can be controlled by the coordination ability of the central nitrogen of the supporting bis-methylbenzimidazolyl ligand.

原文英語
頁(從 - 到)2563-2570
頁數8
期刊Journal of the Chemical Society. Dalton Transactions
發行號24
DOIs
出版狀態已發佈 - 2007 四月 17

ASJC Scopus subject areas

  • 化學 (全部)

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