摘要
Addition of aluminum chloride to the (η4-cyclohexadiene)Fe(CO)3 complex bearing an acid chloride side chain at C-5 gives a cyclic keto complex, whereas Lewis acid assisted intramolecular cyclization of acyclic (η4-butadiene)Fe(CO)3 complexes containing an aldehyde, an ester, or a nitrile functionality produces (σ,η3-allyl)tricarbonyliron complexes. Treatments of the (η4-butadiene)Fe(CO)3 complexes bearing a chromium carbene moiety in refluxing toluene lead to formation of furan derivatives by intramolecular addition of the diene ligand to the chromium carbene carbon center.
原文 | 英語 |
---|---|
頁(從 - 到) | 4435-4444 |
頁數 | 10 |
期刊 | Organometallics |
卷 | 16 |
發行號 | 20 |
DOIs | |
出版狀態 | 已發佈 - 1997 9月 30 |
ASJC Scopus subject areas
- 物理與理論化學
- 有機化學
- 無機化學