Lewis acid promoted intramolecular cyclization of (η4-diene)Fe(CO)3 complexes bearing functionalized side chains

Ming Chang P. Yeh*, L. W. Chuang, S. C. Chang, M. L. Lai, C. C. Chou

*此作品的通信作者

研究成果: 雜誌貢獻期刊論文同行評審

18 引文 斯高帕斯(Scopus)

摘要

Addition of aluminum chloride to the (η4-cyclohexadiene)Fe(CO)3 complex bearing an acid chloride side chain at C-5 gives a cyclic keto complex, whereas Lewis acid assisted intramolecular cyclization of acyclic (η4-butadiene)Fe(CO)3 complexes containing an aldehyde, an ester, or a nitrile functionality produces (σ,η3-allyl)tricarbonyliron complexes. Treatments of the (η4-butadiene)Fe(CO)3 complexes bearing a chromium carbene moiety in refluxing toluene lead to formation of furan derivatives by intramolecular addition of the diene ligand to the chromium carbene carbon center.

原文英語
頁(從 - 到)4435-4444
頁數10
期刊Organometallics
16
發行號20
DOIs
出版狀態已發佈 - 1997 九月 30

ASJC Scopus subject areas

  • 物理與理論化學
  • 有機化學
  • 無機化學

指紋

深入研究「Lewis acid promoted intramolecular cyclization of (η<sup>4</sup>-diene)Fe(CO)<sub>3</sub> complexes bearing functionalized side chains」主題。共同形成了獨特的指紋。

引用此