Iron carbonyl cluster-incorporated Cu(i) NHC complexes in homocoupling of arylboronic acids: An effective [TeFe3(CO)9]2- ligand

Chien Nan Lin; Chung Yi Huang; Chia Chi Yu; Yen Ming Chen; Wei Ming Ke; Guan Jung Wang; Gon Ann Lee; Minghuey Shieh

doi:10.1039/c5dt03242c

Iron carbonyl cluster-incorporated Cu(i) NHC complexes in homocoupling of arylboronic acids: An effective [TeFe₃(CO)₉]^2- ligand

Chien Nan Lin, Chung Yi Huang, Chia Chi Yu, Yen Ming Chen, Wei Ming Ke, Guan Jung Wang, Gon Ann Lee, Minghuey Shieh^*

^*此作品的通信作者

化學系

研究成果: 雜誌貢獻 › 期刊論文 › 同行評審

25 引文斯高帕斯（Scopus）

摘要

A new type of TeFe₃(CO)₉-incorporated dicopper NHC complex was obtained directly from one-pot reactions. By the introduction of the cluster anion [TeFe₃(CO)₉]^2- and NHCs as the ligands, these di-Cu(i)-based complexes exhibited pronounced catalytic activities toward the homocoupling of arylboronic acids with low Cu loadings and high yields (up to 98%).

原文	英語
頁（從 - 到）	16675-16679
頁數	5
期刊	Dalton Transactions
卷	44
發行號	38
DOIs	https://doi.org/10.1039/c5dt03242c
出版狀態	已發佈 - 2015 8月 25

ASJC Scopus subject areas

無機化學

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10.1039/c5dt03242c

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Link to publication in Scopus

CCDC 1011560: Experimental Crystal Structure Determination
Lin, C.-N. (Creator), Huang, C.-Y. (Creator), Yu, C.-C. (Creator), Chen, Y.-M. (Creator), Ke, W.-M. (Creator), Wang, G.-J. (Creator), Lee, G.-A. (Creator) & Shieh, M. (Creator), Unknown Publisher, 2015
DOI: 10.5517/cc12ylzl, http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/cc12ylzl&sid=DataCite
資料集: Dataset
CCDC 1011562: Experimental Crystal Structure Determination
Lin, C.-N. (Creator), Huang, C.-Y. (Creator), Yu, C.-C. (Creator), Chen, Y.-M. (Creator), Ke, W.-M. (Creator), Wang, G.-J. (Creator), Lee, G.-A. (Creator) & Shieh, M. (Creator), Unknown Publisher, 2015
DOI: 10.5517/cc12ym1p, http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/cc12ym1p&sid=DataCite
資料集: Dataset
CCDC 1011563: Experimental Crystal Structure Determination
Lin, C.-N. (Creator), Huang, C.-Y. (Creator), Yu, C.-C. (Creator), Chen, Y.-M. (Creator), Ke, W.-M. (Creator), Wang, G.-J. (Creator), Lee, G.-A. (Creator) & Shieh, M. (Creator), Unknown Publisher, 2015
DOI: 10.5517/cc12ym2q, http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/cc12ym2q&sid=DataCite
資料集: Dataset

引用此

@article{56802a47de314a1889b562318097920e,

title = "Iron carbonyl cluster-incorporated Cu(i) NHC complexes in homocoupling of arylboronic acids: An effective [TeFe3(CO)9]2- ligand",

abstract = "A new type of TeFe3(CO)9-incorporated dicopper NHC complex was obtained directly from one-pot reactions. By the introduction of the cluster anion [TeFe3(CO)9]2- and NHCs as the ligands, these di-Cu(i)-based complexes exhibited pronounced catalytic activities toward the homocoupling of arylboronic acids with low Cu loadings and high yields (up to 98%).",

author = "Lin, {Chien Nan} and Huang, {Chung Yi} and Yu, {Chia Chi} and Chen, {Yen Ming} and Ke, {Wei Ming} and Wang, {Guan Jung} and Lee, {Gon Ann} and Minghuey Shieh",

note = "Publisher Copyright: {\textcopyright} The Royal Society of Chemistry 2015.",

year = "2015",

month = aug,

day = "25",

doi = "10.1039/c5dt03242c",

language = "English",

volume = "44",

pages = "16675--16679",

journal = "Dalton Transactions",

issn = "1477-9226",

publisher = "Royal Society of Chemistry",

number = "38",

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TY - JOUR

T1 - Iron carbonyl cluster-incorporated Cu(i) NHC complexes in homocoupling of arylboronic acids

T2 - An effective [TeFe3(CO)9]2- ligand

AU - Lin, Chien Nan

AU - Huang, Chung Yi

AU - Yu, Chia Chi

AU - Chen, Yen Ming

AU - Ke, Wei Ming

AU - Wang, Guan Jung

AU - Lee, Gon Ann

AU - Shieh, Minghuey

PY - 2015/8/25

Y1 - 2015/8/25

N2 - A new type of TeFe3(CO)9-incorporated dicopper NHC complex was obtained directly from one-pot reactions. By the introduction of the cluster anion [TeFe3(CO)9]2- and NHCs as the ligands, these di-Cu(i)-based complexes exhibited pronounced catalytic activities toward the homocoupling of arylboronic acids with low Cu loadings and high yields (up to 98%).

AB - A new type of TeFe3(CO)9-incorporated dicopper NHC complex was obtained directly from one-pot reactions. By the introduction of the cluster anion [TeFe3(CO)9]2- and NHCs as the ligands, these di-Cu(i)-based complexes exhibited pronounced catalytic activities toward the homocoupling of arylboronic acids with low Cu loadings and high yields (up to 98%).

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U2 - 10.1039/c5dt03242c

DO - 10.1039/c5dt03242c

M3 - Article

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SN - 1477-9226

VL - 44

SP - 16675

EP - 16679

JO - Dalton Transactions

JF - Dalton Transactions

IS - 38

ER -

Iron carbonyl cluster-incorporated Cu(i) NHC complexes in homocoupling of arylboronic acids: An effective [TeFe3(CO)9]2- ligand

摘要

ASJC Scopus subject areas

存取文件

其它文件與鏈接

指紋

資料集

CCDC 1011560: Experimental Crystal Structure Determination

CCDC 1011562: Experimental Crystal Structure Determination

CCDC 1011563: Experimental Crystal Structure Determination

引用此

Iron carbonyl cluster-incorporated Cu(i) NHC complexes in homocoupling of arylboronic acids: An effective [TeFe₃(CO)₉]^2- ligand