Intramolecular friedel-crafts acylation of acyclic (η4-diene)fe(co)3 complexes

Ming Chang P. Yeh; Suen Chi Chang; Ching Ju Chang

doi:10.1016/S0022-328X(99)00747-0

Intramolecular friedel-crafts acylation of acyclic (η⁴-diene)fe(co)₃ complexes

Ming Chang P. Yeh^*
, Suen Chi Chang
, Ching Ju Chang

^*此作品的通信作者

化學系

研究成果: 雜誌貢獻 › 期刊論文 › 同行評審

4 引文斯高帕斯（Scopus）

摘要

Intramolecular cyclization of (η⁴-diene)Fe(CO)₃ complexes bearing a carboxylic acid chloride functionality at the terminal side chain of the diene ligand produces (σ, η³-allyl)Fe(CO)₃ complexes, whereas treatment of the acid cholride complexes with Et₃N and A1C1₃ provides (η⁴-diene)Fe(CO)₃ complexes containing a cyclopentanone moiety.

原文	英語
頁（從 - 到）	128-134
頁數	7
期刊	Journal of Organometallic Chemistry
卷	599
發行號	2
DOIs	https://doi.org/10.1016/S0022-328X(99)00747-0
出版狀態	已發佈 - 2000 4月 15

ASJC Scopus subject areas

生物化學
物理與理論化學
有機化學
無機化學
材料化學

存取文件

10.1016/S0022-328X(99)00747-0

其它文件與鏈接

CCDC 137673: Experimental Crystal Structure Determination
Yeh, M.-C. P. (Creator), Chang, S.-C. (Creator) & Chang, C.-J. (Creator), Cambridge Crystallographic Data Centre, 2003
DOI: 10.5517/cc4m822, http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/cc4m822&sid=DataCite
資料集: Dataset

引用此

@article{88e082fc9bbf467d80305fd595136a63,

title = "Intramolecular friedel-crafts acylation of acyclic (η4-diene)fe(co)3 complexes",

abstract = "Intramolecular cyclization of (η4-diene)Fe(CO)3 complexes bearing a carboxylic acid chloride functionality at the terminal side chain of the diene ligand produces (σ, η3-allyl)Fe(CO)3 complexes, whereas treatment of the acid cholride complexes with Et3N and A1C13 provides (η4-diene)Fe(CO)3 complexes containing a cyclopentanone moiety.",

keywords = "Cyclopentanone, Diene, Friedel-crafts acylation, Intramolecular, Iron",

author = "Yeh, \{Ming Chang P.\} and Chang, \{Suen Chi\} and Chang, \{Ching Ju\}",

note = "Funding Information: We thank the National Science Council (88-2113-M-003-010) of the Republic of China for financial support. ",

year = "2000",

month = apr,

day = "15",

doi = "10.1016/S0022-328X(99)00747-0",

language = "English",

volume = "599",

pages = "128--134",

journal = "Journal of Organometallic Chemistry",

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TY - JOUR

T1 - Intramolecular friedel-crafts acylation of acyclic (η4-diene)fe(co)3 complexes

AU - Yeh, Ming Chang P.

AU - Chang, Suen Chi

AU - Chang, Ching Ju

N1 - Funding Information: We thank the National Science Council (88-2113-M-003-010) of the Republic of China for financial support.

PY - 2000/4/15

Y1 - 2000/4/15

N2 - Intramolecular cyclization of (η4-diene)Fe(CO)3 complexes bearing a carboxylic acid chloride functionality at the terminal side chain of the diene ligand produces (σ, η3-allyl)Fe(CO)3 complexes, whereas treatment of the acid cholride complexes with Et3N and A1C13 provides (η4-diene)Fe(CO)3 complexes containing a cyclopentanone moiety.

AB - Intramolecular cyclization of (η4-diene)Fe(CO)3 complexes bearing a carboxylic acid chloride functionality at the terminal side chain of the diene ligand produces (σ, η3-allyl)Fe(CO)3 complexes, whereas treatment of the acid cholride complexes with Et3N and A1C13 provides (η4-diene)Fe(CO)3 complexes containing a cyclopentanone moiety.

KW - Cyclopentanone

KW - Diene

KW - Friedel-crafts acylation

KW - Intramolecular

KW - Iron

UR - https://www.scopus.com/pages/publications/0034654731

UR - https://www.scopus.com/pages/publications/0034654731#tab=citedBy

U2 - 10.1016/S0022-328X(99)00747-0

DO - 10.1016/S0022-328X(99)00747-0

M3 - Article

AN - SCOPUS:0034654731

SN - 0022-328X

VL - 599

SP - 128

EP - 134

JO - Journal of Organometallic Chemistry

JF - Journal of Organometallic Chemistry

IS - 2

ER -

Intramolecular friedel-crafts acylation of acyclic (η4-diene)fe(co)3 complexes

摘要

ASJC Scopus subject areas

存取文件

其它文件與鏈接

指紋

資料集

CCDC 137673: Experimental Crystal Structure Determination

引用此

Intramolecular friedel-crafts acylation of acyclic (η⁴-diene)fe(co)₃ complexes