Intramolecular 1,3-dipolar cycloaddition of cyclo-1,3-diene-tethered nitrile oxides

Ming Chang P. Yeh; Chi Fen Jou; Wei Tzou Yeh; Da Yu Chiu; N. Ravi Kumar Reddy

doi:10.1016/j.tet.2004.10.078

Intramolecular 1,3-dipolar cycloaddition of cyclo-1,3-diene-tethered nitrile oxides

Ming Chang P. Yeh
, Chi Fen Jou
, Wei Tzou Yeh
, Da Yu Chiu
, N. Ravi Kumar Reddy

化學系

研究成果: 雜誌貢獻 › 期刊論文 › 同行評審

21 引文斯高帕斯（Scopus）

摘要

Intramolecular 1,3-dipolar cycloaddition of cyclo-1,3-diene- and -1,3,5-triene-tethered nitrile oxides gave tricyclic isoxazolines as a single stereoisomer in most cases. The relative stereochemistry of tricycle-fused isoxazolines resulting from 1,3-dipolar cycloaddition of cyclo-1,3-diene- tethered nitrile oxides is cis-cis, whereas from cyclohepta-1,3,5-triene- tethered nitrile oxides the cis-trans isomer predominates.

原文	英語
頁（從 - 到）	493-500
頁數	8
期刊	Tetrahedron
卷	61
發行號	2
DOIs	https://doi.org/10.1016/j.tet.2004.10.078
出版狀態	已發佈 - 2005 1月 10

ASJC Scopus subject areas

生物化學
藥物發現
有機化學

存取文件

10.1016/j.tet.2004.10.078

其它文件與鏈接

CCDC 248701: Experimental Crystal Structure Determination
Yeh, M.-C. P. (Creator), Jou, C.-F. (Creator), Yeh, W.-T. (Creator), Chiu, D.-Y. (Creator) & Reddy, N. R. K. (Creator), Unknown Publisher, 2005
DOI: 10.5517/cc8bsmz, http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/cc8bsmz&sid=DataCite
資料集: Dataset
CCDC 248697: Experimental Crystal Structure Determination
Yeh, M.-C. P. (Creator), Jou, C.-F. (Creator), Yeh, W.-T. (Creator), Chiu, D.-Y. (Creator) & Reddy, N. R. K. (Creator), Unknown Publisher, 2005
DOI: 10.5517/cc8bshv, http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/cc8bshv&sid=DataCite
資料集: Dataset
CCDC 248696: Experimental Crystal Structure Determination
Yeh, M.-C. P. (Creator), Jou, C.-F. (Creator), Yeh, W.-T. (Creator), Chiu, D.-Y. (Creator) & Reddy, N. R. K. (Creator), Unknown Publisher, 2005
DOI: 10.5517/cc8bsgt, http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/cc8bsgt&sid=DataCite
資料集: Dataset

引用此

@article{bafdccf4d286408e9167b5f3fdeccae2,

title = "Intramolecular 1,3-dipolar cycloaddition of cyclo-1,3-diene-tethered nitrile oxides",

abstract = "Intramolecular 1,3-dipolar cycloaddition of cyclo-1,3-diene- and -1,3,5-triene-tethered nitrile oxides gave tricyclic isoxazolines as a single stereoisomer in most cases. The relative stereochemistry of tricycle-fused isoxazolines resulting from 1,3-dipolar cycloaddition of cyclo-1,3-diene- tethered nitrile oxides is cis-cis, whereas from cyclohepta-1,3,5-triene- tethered nitrile oxides the cis-trans isomer predominates.",

keywords = "Aldoximes, Cyclohepta-1,3,5-trienes, Cyclohexa- and cyclohepta-1,3-dienes, Isoxazolines",

author = "Yeh, \{Ming Chang P.\} and Jou, \{Chi Fen\} and Yeh, \{Wei Tzou\} and Chiu, \{Da Yu\} and Reddy, \{N. Ravi Kumar\}",

note = "Funding Information: This work was supported by grants from National Taiwan Normal University (ORD 92-2) and National Science Council (NSC 92-2113-M-003-009). ",

year = "2005",

month = jan,

day = "10",

doi = "10.1016/j.tet.2004.10.078",

language = "English",

volume = "61",

pages = "493--500",

journal = "Tetrahedron",

issn = "0040-4020",

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T1 - Intramolecular 1,3-dipolar cycloaddition of cyclo-1,3-diene-tethered nitrile oxides

AU - Yeh, Ming Chang P.

AU - Jou, Chi Fen

AU - Yeh, Wei Tzou

AU - Chiu, Da Yu

AU - Reddy, N. Ravi Kumar

N1 - Funding Information: This work was supported by grants from National Taiwan Normal University (ORD 92-2) and National Science Council (NSC 92-2113-M-003-009).

PY - 2005/1/10

Y1 - 2005/1/10

N2 - Intramolecular 1,3-dipolar cycloaddition of cyclo-1,3-diene- and -1,3,5-triene-tethered nitrile oxides gave tricyclic isoxazolines as a single stereoisomer in most cases. The relative stereochemistry of tricycle-fused isoxazolines resulting from 1,3-dipolar cycloaddition of cyclo-1,3-diene- tethered nitrile oxides is cis-cis, whereas from cyclohepta-1,3,5-triene- tethered nitrile oxides the cis-trans isomer predominates.

AB - Intramolecular 1,3-dipolar cycloaddition of cyclo-1,3-diene- and -1,3,5-triene-tethered nitrile oxides gave tricyclic isoxazolines as a single stereoisomer in most cases. The relative stereochemistry of tricycle-fused isoxazolines resulting from 1,3-dipolar cycloaddition of cyclo-1,3-diene- tethered nitrile oxides is cis-cis, whereas from cyclohepta-1,3,5-triene- tethered nitrile oxides the cis-trans isomer predominates.

KW - Aldoximes

KW - Cyclohepta-1,3,5-trienes

KW - Cyclohexa- and cyclohepta-1,3-dienes

KW - Isoxazolines

UR - https://www.scopus.com/pages/publications/9744222886

UR - https://www.scopus.com/pages/publications/9744222886#tab=citedBy

U2 - 10.1016/j.tet.2004.10.078

DO - 10.1016/j.tet.2004.10.078

M3 - Article

AN - SCOPUS:9744222886

SN - 0040-4020

VL - 61

SP - 493

EP - 500

JO - Tetrahedron

JF - Tetrahedron

IS - 2

ER -

Intramolecular 1,3-dipolar cycloaddition of cyclo-1,3-diene-tethered nitrile oxides

摘要

ASJC Scopus subject areas

存取文件

其它文件與鏈接

指紋

資料集

CCDC 248701: Experimental Crystal Structure Determination

CCDC 248697: Experimental Crystal Structure Determination

CCDC 248696: Experimental Crystal Structure Determination

引用此