Highly interpenetrated diamondoid nets of Zn(ii) and Cd(ii) coordination networks from mixed ligands

Jian Jr Cheng; Ya Ting Chang; Chia Jun Wu; Yi Fen Hsu; Chia Her Lin; Davide M. Proserpio; Jhy Der Chen

doi:10.1039/c1ce06019h

Highly interpenetrated diamondoid nets of Zn(ii) and Cd(ii) coordination networks from mixed ligands

Jian Jr Cheng
, Ya Ting Chang
, Chia Jun Wu
, Yi Fen Hsu
, Chia Her Lin
, Davide M. Proserpio^*
, Jhy Der Chen

^*此作品的通信作者

研究成果: 雜誌貢獻 › 期刊論文 › 同行評審

91 引文斯高帕斯（Scopus）

摘要

The syntheses, structures and thermal properties of three coordination networks [Zn(L¹)(1,4-BDC)]·H₂O (L¹ = N,N′-di(4-pyridyl)adipoamide; 1,4-H₂BDC = 1,4- benzenedicarboxylic acid), 1, [Cd(L¹)(1,4-BDC)]·2H ₂O, 2, and [Zn₂(L²)(1,4-BDC) ₂]·2CH₃OH (L² = N,N′-di(4-pyridyl) dodecanamide), 3, are reported. Complexes 1 and 2 show the dia topology with the rare 8- and 9-fold interpenetrating modes, respectively, while 3 exhibits an interpenetrating 3-fold framework with the pcu Zn₂(COO)₂ dimer decorated topology. Complex 2 shows the maximum number of interpenetration presently known for interpenetrating diamondoid networks of coordination networks containing mixed spacer ligands.

原文	英語
頁（從 - 到）	537-543
頁數	7
期刊	CrystEngComm
卷	14
發行號	2
DOIs	https://doi.org/10.1039/c1ce06019h
出版狀態	已發佈 - 2012 1月 21
對外發佈	是

ASJC Scopus subject areas

一般化學
一般材料科學
凝聚態物理學

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10.1039/c1ce06019h

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@article{68f08ee2377e488e8843ed474bd7457b,

title = "Highly interpenetrated diamondoid nets of Zn(ii) and Cd(ii) coordination networks from mixed ligands",

abstract = "The syntheses, structures and thermal properties of three coordination networks [Zn(L1)(1,4-BDC)]·H2O (L1 = N,N′-di(4-pyridyl)adipoamide; 1,4-H2BDC = 1,4- benzenedicarboxylic acid), 1, [Cd(L1)(1,4-BDC)]·2H 2O, 2, and [Zn2(L2)(1,4-BDC) 2]·2CH3OH (L2 = N,N′-di(4-pyridyl) dodecanamide), 3, are reported. Complexes 1 and 2 show the dia topology with the rare 8- and 9-fold interpenetrating modes, respectively, while 3 exhibits an interpenetrating 3-fold framework with the pcu Zn2(COO)2 dimer decorated topology. Complex 2 shows the maximum number of interpenetration presently known for interpenetrating diamondoid networks of coordination networks containing mixed spacer ligands.",

author = "Cheng, \{Jian Jr\} and Chang, \{Ya Ting\} and Wu, \{Chia Jun\} and Hsu, \{Yi Fen\} and Lin, \{Chia Her\} and Proserpio, \{Davide M.\} and Chen, \{Jhy Der\}",

year = "2012",

month = jan,

day = "21",

doi = "10.1039/c1ce06019h",

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T1 - Highly interpenetrated diamondoid nets of Zn(ii) and Cd(ii) coordination networks from mixed ligands

AU - Cheng, Jian Jr

AU - Chang, Ya Ting

AU - Wu, Chia Jun

AU - Hsu, Yi Fen

AU - Lin, Chia Her

AU - Proserpio, Davide M.

AU - Chen, Jhy Der

PY - 2012/1/21

Y1 - 2012/1/21

N2 - The syntheses, structures and thermal properties of three coordination networks [Zn(L1)(1,4-BDC)]·H2O (L1 = N,N′-di(4-pyridyl)adipoamide; 1,4-H2BDC = 1,4- benzenedicarboxylic acid), 1, [Cd(L1)(1,4-BDC)]·2H 2O, 2, and [Zn2(L2)(1,4-BDC) 2]·2CH3OH (L2 = N,N′-di(4-pyridyl) dodecanamide), 3, are reported. Complexes 1 and 2 show the dia topology with the rare 8- and 9-fold interpenetrating modes, respectively, while 3 exhibits an interpenetrating 3-fold framework with the pcu Zn2(COO)2 dimer decorated topology. Complex 2 shows the maximum number of interpenetration presently known for interpenetrating diamondoid networks of coordination networks containing mixed spacer ligands.

AB - The syntheses, structures and thermal properties of three coordination networks [Zn(L1)(1,4-BDC)]·H2O (L1 = N,N′-di(4-pyridyl)adipoamide; 1,4-H2BDC = 1,4- benzenedicarboxylic acid), 1, [Cd(L1)(1,4-BDC)]·2H 2O, 2, and [Zn2(L2)(1,4-BDC) 2]·2CH3OH (L2 = N,N′-di(4-pyridyl) dodecanamide), 3, are reported. Complexes 1 and 2 show the dia topology with the rare 8- and 9-fold interpenetrating modes, respectively, while 3 exhibits an interpenetrating 3-fold framework with the pcu Zn2(COO)2 dimer decorated topology. Complex 2 shows the maximum number of interpenetration presently known for interpenetrating diamondoid networks of coordination networks containing mixed spacer ligands.

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U2 - 10.1039/c1ce06019h

DO - 10.1039/c1ce06019h

M3 - Article

AN - SCOPUS:84555179083

SN - 1466-8033

VL - 14

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JO - CrystEngComm

JF - CrystEngComm

IS - 2

ER -

Highly interpenetrated diamondoid nets of Zn(ii) and Cd(ii) coordination networks from mixed ligands

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