TY - JOUR
T1 - Highly interpenetrated diamondoid nets of Zn(ii) and Cd(ii) coordination networks from mixed ligands
AU - Cheng, Jian Jr
AU - Chang, Ya Ting
AU - Wu, Chia Jun
AU - Hsu, Yi Fen
AU - Lin, Chia Her
AU - Proserpio, Davide M.
AU - Chen, Jhy Der
PY - 2012/1/21
Y1 - 2012/1/21
N2 - The syntheses, structures and thermal properties of three coordination networks [Zn(L1)(1,4-BDC)]·H2O (L1 = N,N′-di(4-pyridyl)adipoamide; 1,4-H2BDC = 1,4- benzenedicarboxylic acid), 1, [Cd(L1)(1,4-BDC)]·2H 2O, 2, and [Zn2(L2)(1,4-BDC) 2]·2CH3OH (L2 = N,N′-di(4-pyridyl) dodecanamide), 3, are reported. Complexes 1 and 2 show the dia topology with the rare 8- and 9-fold interpenetrating modes, respectively, while 3 exhibits an interpenetrating 3-fold framework with the pcu Zn2(COO)2 dimer decorated topology. Complex 2 shows the maximum number of interpenetration presently known for interpenetrating diamondoid networks of coordination networks containing mixed spacer ligands.
AB - The syntheses, structures and thermal properties of three coordination networks [Zn(L1)(1,4-BDC)]·H2O (L1 = N,N′-di(4-pyridyl)adipoamide; 1,4-H2BDC = 1,4- benzenedicarboxylic acid), 1, [Cd(L1)(1,4-BDC)]·2H 2O, 2, and [Zn2(L2)(1,4-BDC) 2]·2CH3OH (L2 = N,N′-di(4-pyridyl) dodecanamide), 3, are reported. Complexes 1 and 2 show the dia topology with the rare 8- and 9-fold interpenetrating modes, respectively, while 3 exhibits an interpenetrating 3-fold framework with the pcu Zn2(COO)2 dimer decorated topology. Complex 2 shows the maximum number of interpenetration presently known for interpenetrating diamondoid networks of coordination networks containing mixed spacer ligands.
UR - http://www.scopus.com/inward/record.url?scp=84555179083&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=84555179083&partnerID=8YFLogxK
U2 - 10.1039/c1ce06019h
DO - 10.1039/c1ce06019h
M3 - Article
AN - SCOPUS:84555179083
VL - 14
SP - 537
EP - 543
JO - CrystEngComm
JF - CrystEngComm
SN - 1466-8033
IS - 2
ER -