Highly interpenetrated diamondoid nets of Zn(ii) and Cd(ii) coordination networks from mixed ligands

Jian Jr Cheng, Ya Ting Chang, Chia Jun Wu, Yi Fen Hsu, Chia Her Lin, Davide M. Proserpio*, Jhy Der Chen

*此作品的通信作者

研究成果: 雜誌貢獻期刊論文同行評審

89 引文 斯高帕斯(Scopus)

摘要

The syntheses, structures and thermal properties of three coordination networks [Zn(L1)(1,4-BDC)]·H2O (L1 = N,N′-di(4-pyridyl)adipoamide; 1,4-H2BDC = 1,4- benzenedicarboxylic acid), 1, [Cd(L1)(1,4-BDC)]·2H 2O, 2, and [Zn2(L2)(1,4-BDC) 2]·2CH3OH (L2 = N,N′-di(4-pyridyl) dodecanamide), 3, are reported. Complexes 1 and 2 show the dia topology with the rare 8- and 9-fold interpenetrating modes, respectively, while 3 exhibits an interpenetrating 3-fold framework with the pcu Zn2(COO)2 dimer decorated topology. Complex 2 shows the maximum number of interpenetration presently known for interpenetrating diamondoid networks of coordination networks containing mixed spacer ligands.

原文英語
頁(從 - 到)537-543
頁數7
期刊CrystEngComm
14
發行號2
DOIs
出版狀態已發佈 - 2012 一月 21
對外發佈

ASJC Scopus subject areas

  • 化學 (全部)
  • 材料科學(全部)
  • 凝聚態物理學

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