Highly efficient proline ester-based nickel catalysts for Michael addition of thiophenols to α,β-enones

Way Zen Lee; Chien Wei Chiang; Girish M. Kulkarni; Ting Shen Kuo

doi:10.1002/jccs.201200386

Highly efficient proline ester-based nickel catalysts for Michael addition of thiophenols to α,β-enones

Way Zen Lee^*, Chien Wei Chiang, Girish M. Kulkarni, Ting Shen Kuo

^*此作品的通信作者

化學系

研究成果: 雜誌貢獻 › 期刊論文 › 同行評審

3 引文斯高帕斯（Scopus）

摘要

Two N₃O₂ pentadentate ligands, BMPP and BPPP, were prepared for synthesizing highly efficient nickel catalysts, [Ni(BMPP)(CH ₃CN)](ClO₄)₂ (1) and [Ni(BPPP)(CH ₃CN)](BPh₄)(ClO₄) (2), for thia-Michael addition of thiophenols to α,β-enones. X-ray structures of 1 and 2 revealed that a labile CH3CN molecule was bound to the nickel center of the catalysts. ESI-MS spectroscopy indicated that thiolate replaced the bound CH3CN molecule and coordinated to the nickel center during the catalytic cycle.

原文	英語
頁（從 - 到）	245-250
頁數	6
期刊	Journal of the Chinese Chemical Society
卷	60
發行號	3
DOIs	https://doi.org/10.1002/jccs.201200386
出版狀態	已發佈 - 2013 3月

ASJC Scopus subject areas

化學 (全部)

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10.1002/jccs.201200386

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title = "Highly efficient proline ester-based nickel catalysts for Michael addition of thiophenols to α,β-enones",

abstract = "Two N3O2 pentadentate ligands, BMPP and BPPP, were prepared for synthesizing highly efficient nickel catalysts, [Ni(BMPP)(CH 3CN)](ClO4)2 (1) and [Ni(BPPP)(CH 3CN)](BPh4)(ClO4) (2), for thia-Michael addition of thiophenols to α,β-enones. X-ray structures of 1 and 2 revealed that a labile CH3CN molecule was bound to the nickel center of the catalysts. ESI-MS spectroscopy indicated that thiolate replaced the bound CH3CN molecule and coordinated to the nickel center during the catalytic cycle.",

keywords = "Conjugate addition, Nickel complexes, Proline derivatives, Pyridine derivatives, Thia-Michael addition",

author = "Lee, {Way Zen} and Chiang, {Chien Wei} and Kulkarni, {Girish M.} and Kuo, {Ting Shen}",

year = "2013",

month = mar,

doi = "10.1002/jccs.201200386",

language = "English",

volume = "60",

pages = "245--250",

journal = "Journal of the Chinese Chemical Society",

issn = "0009-4536",

publisher = "Chinese Chemical Society",

number = "3",

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TY - JOUR

T1 - Highly efficient proline ester-based nickel catalysts for Michael addition of thiophenols to α,β-enones

AU - Lee, Way Zen

AU - Chiang, Chien Wei

AU - Kulkarni, Girish M.

AU - Kuo, Ting Shen

PY - 2013/3

Y1 - 2013/3

N2 - Two N3O2 pentadentate ligands, BMPP and BPPP, were prepared for synthesizing highly efficient nickel catalysts, [Ni(BMPP)(CH 3CN)](ClO4)2 (1) and [Ni(BPPP)(CH 3CN)](BPh4)(ClO4) (2), for thia-Michael addition of thiophenols to α,β-enones. X-ray structures of 1 and 2 revealed that a labile CH3CN molecule was bound to the nickel center of the catalysts. ESI-MS spectroscopy indicated that thiolate replaced the bound CH3CN molecule and coordinated to the nickel center during the catalytic cycle.

AB - Two N3O2 pentadentate ligands, BMPP and BPPP, were prepared for synthesizing highly efficient nickel catalysts, [Ni(BMPP)(CH 3CN)](ClO4)2 (1) and [Ni(BPPP)(CH 3CN)](BPh4)(ClO4) (2), for thia-Michael addition of thiophenols to α,β-enones. X-ray structures of 1 and 2 revealed that a labile CH3CN molecule was bound to the nickel center of the catalysts. ESI-MS spectroscopy indicated that thiolate replaced the bound CH3CN molecule and coordinated to the nickel center during the catalytic cycle.

KW - Conjugate addition

KW - Nickel complexes

KW - Proline derivatives

KW - Pyridine derivatives

KW - Thia-Michael addition

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U2 - 10.1002/jccs.201200386

DO - 10.1002/jccs.201200386

M3 - Article

AN - SCOPUS:84878274457

VL - 60

SP - 245

EP - 250

JO - Journal of the Chinese Chemical Society

JF - Journal of the Chinese Chemical Society

SN - 0009-4536

IS - 3

ER -

Highly efficient proline ester-based nickel catalysts for Michael addition of thiophenols to α,β-enones

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