Free-Radical Reactions of Trialkylboranes with β-Nitrostyrenes to Generate Alkenes

Ching Fa Yao, Cheng Ming Chu, Ju Tsung Liu

研究成果: 雜誌貢獻期刊論文同行評審

38 引文 斯高帕斯(Scopus)

摘要

β-Nitrostyrenes 1 react with trialkylboranes under a nitrogen atmosphere to generate high yields of alkenes 2. The mechanism is proposed to be a free-radical reaction via NO2/alkyl substitution since the reaction is stimulated by the presence of a trace of oxygen in the nitrogen or tert-butyl peroxide or by photolysis and is retarded or inhibited by the addition of galvinoxyl to the solution.

原文英語
頁(從 - 到)719-722
頁數4
期刊Journal of Organic Chemistry
63
發行號3
DOIs
出版狀態已發佈 - 1998 二月 6

ASJC Scopus subject areas

  • Organic Chemistry

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