Formation of a sulfur-atom-inserted N-confused porphyrin iron nitrosyl complex by denitrosation and C-S bond cleavage of an S-nitrosothiol

Chen Hsiung Hung; Wei Min Ching; Gao Fong Chang; Chuan Hung Chuang; Han Wei Chu; Way Zen Lee

doi:10.1021/ic7018378

Formation of a sulfur-atom-inserted N-confused porphyrin iron nitrosyl complex by denitrosation and C-S bond cleavage of an S-nitrosothiol

Chen Hsiung Hung^*, Wei Min Ching, Gao Fong Chang, Chuan Hung Chuang, Han Wei Chu, Way Zen Lee

^*此作品的通信作者

化學系

研究成果: 雜誌貢獻 › 期刊論文 › 同行評審

14 引文斯高帕斯（Scopus）

摘要

The reaction of nitrosothiol, Ph₃CSNO, with a divalent iron N-confused porphyrin complex, Fe(HCTPPH)Br, yields a {Fe(NO)}⁶ iron nitrosyl complex with a sulfur atom inserted in the Fe-C bond. The crystal structure reveals a bent Fe-N-O geometry and an η²-(C,S) bonding mode between iron and the C-S bond. A reaction mechanism involving a transnitrosation and a nitrosothiol C-S bond cleavage is proposed.

原文	英語
頁（從 - 到）	10941-10943
頁數	3
期刊	Inorganic Chemistry
卷	46
發行號	26
DOIs	https://doi.org/10.1021/ic7018378
出版狀態	已發佈 - 2007 12月 24

ASJC Scopus subject areas

物理與理論化學
無機化學

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10.1021/ic7018378

其它文件與鏈接

CCDC 826296: Experimental Crystal Structure Determination
Hung, C. (Creator), Ching, W. (Creator), Chang, G. (Creator), Chuang, C. (Creator), Chu, H. (Creator) & Lee, W. (Creator), Unknown Publisher, 2011
DOI: 10.5517/ccwqtq3, http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/ccwqtq3&sid=DataCite
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title = "Formation of a sulfur-atom-inserted N-confused porphyrin iron nitrosyl complex by denitrosation and C-S bond cleavage of an S-nitrosothiol",

abstract = "The reaction of nitrosothiol, Ph3CSNO, with a divalent iron N-confused porphyrin complex, Fe(HCTPPH)Br, yields a {Fe(NO)}6 iron nitrosyl complex with a sulfur atom inserted in the Fe-C bond. The crystal structure reveals a bent Fe-N-O geometry and an η2-(C,S) bonding mode between iron and the C-S bond. A reaction mechanism involving a transnitrosation and a nitrosothiol C-S bond cleavage is proposed.",

author = "Hung, {Chen Hsiung} and Ching, {Wei Min} and Chang, {Gao Fong} and Chuang, {Chuan Hung} and Chu, {Han Wei} and Lee, {Way Zen}",

year = "2007",

month = dec,

day = "24",

doi = "10.1021/ic7018378",

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T1 - Formation of a sulfur-atom-inserted N-confused porphyrin iron nitrosyl complex by denitrosation and C-S bond cleavage of an S-nitrosothiol

AU - Hung, Chen Hsiung

AU - Ching, Wei Min

AU - Chang, Gao Fong

AU - Chuang, Chuan Hung

AU - Chu, Han Wei

AU - Lee, Way Zen

PY - 2007/12/24

Y1 - 2007/12/24

N2 - The reaction of nitrosothiol, Ph3CSNO, with a divalent iron N-confused porphyrin complex, Fe(HCTPPH)Br, yields a {Fe(NO)}6 iron nitrosyl complex with a sulfur atom inserted in the Fe-C bond. The crystal structure reveals a bent Fe-N-O geometry and an η2-(C,S) bonding mode between iron and the C-S bond. A reaction mechanism involving a transnitrosation and a nitrosothiol C-S bond cleavage is proposed.

AB - The reaction of nitrosothiol, Ph3CSNO, with a divalent iron N-confused porphyrin complex, Fe(HCTPPH)Br, yields a {Fe(NO)}6 iron nitrosyl complex with a sulfur atom inserted in the Fe-C bond. The crystal structure reveals a bent Fe-N-O geometry and an η2-(C,S) bonding mode between iron and the C-S bond. A reaction mechanism involving a transnitrosation and a nitrosothiol C-S bond cleavage is proposed.

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DO - 10.1021/ic7018378

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JO - Inorganic Chemistry

JF - Inorganic Chemistry

IS - 26

ER -

Formation of a sulfur-atom-inserted N-confused porphyrin iron nitrosyl complex by denitrosation and C-S bond cleavage of an S-nitrosothiol

摘要

ASJC Scopus subject areas

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其它文件與鏈接

指紋

資料集

CCDC 826296: Experimental Crystal Structure Determination

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