Ferromagnetic CoPt3 nanowires: Structural evolution from fcc to ordered L12

Ming Chen Hao, Fen Hsin Chia, Yuan Chen Po, Ru Shi Liu, Shu Fen Hu, Chao Yuan Huang, Jyh Fu Lee, Ling Yun Jang

研究成果: 雜誌貢獻文章同行評審

32 引文 斯高帕斯(Scopus)

摘要

This investigation demonstrates the magnetic properties and nanostructures of CoPt3 wire arrays that were fabricated by electrodeposition using a porous alumina template. The X-ray absorption analysis clearly verified the occurrence of a phase transition in CoPt3 nanowires. This phase transition significantly influences the magnetic properties and enhances coercivity and squareness. The phase transition of CoPt3 nanowires was from a random alloy distribution to anisotropically ordered CoPt3 (L12). The thermally induced phase transition of CoPt3 nanowires to ordered L12 CoPt3 through a "cluster-in-cluster" intermediate state via interdiffusion processes is revealed. The mechanism exhibited by these CoPt3 nanowires is proposed to explain the strong correlation between their magnetic character and their atomic distribution.

原文英語
頁(從 - 到)15794-15801
頁數8
期刊Journal of the American Chemical Society
131
發行號43
DOIs
出版狀態已發佈 - 2009 十一月 4

ASJC Scopus subject areas

  • Catalysis
  • Chemistry(all)
  • Biochemistry
  • Colloid and Surface Chemistry

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