Facile and highly efficient method for the C-alkylation of 2-hydroxy-1,4-naphthoquinone to nitroalkenes under catalyst-free 'on water' conditions

Deepak Kumar Barange; Veerababurao Kavala; B. Rama Raju; Chun Wei Kuo; Chi Tseng; Yu Chen Tu; Ching Fa Yao

doi:10.1016/j.tetlet.2009.06.107

Facile and highly efficient method for the C-alkylation of 2-hydroxy-1,4-naphthoquinone to nitroalkenes under catalyst-free 'on water' conditions

Deepak Kumar Barange, Veerababurao Kavala, B. Rama Raju, Chun Wei Kuo, Chi Tseng, Yu Chen Tu, Ching Fa Yao^*

^*此作品的通信作者

化學系

研究成果: 雜誌貢獻 › 期刊論文 › 同行評審

25 引文斯高帕斯（Scopus）

摘要

C-Alkylation of 2-hydroxy-1,4-naphthoquinone to various nitroolefins was achieved under catalyst-free employing 'on water' conditions. The mechanism for the formation can be explained on the basis of dual activation of nitroalkene and 2-hydroxy-1,4-naphthoquinones via hydrogen bonding. Simple reaction conditions, high yields of the products, and environmentally benign medium are attractive features of this method.

原文	英語
頁（從 - 到）	5116-5119
頁數	4
期刊	Tetrahedron Letters
卷	50
發行號	36
DOIs	https://doi.org/10.1016/j.tetlet.2009.06.107
出版狀態	已發佈 - 2009 9月 9

ASJC Scopus subject areas

生物化學
藥物發現
有機化學

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10.1016/j.tetlet.2009.06.107

其它文件與鏈接

CCDC 720909: Experimental Crystal Structure Determination
Barange, D. K. (Creator), Kavala, V. (Creator), Raju, B. R. (Creator), Kuo, C. (Creator), Tseng, C. (Creator), Tu, Y. (Creator) & Yao, C. (Creator), Unknown Publisher, 2010
DOI: 10.5517/ccs6548, http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/ccs6548&sid=DataCite
資料集: Dataset

引用此

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title = "Facile and highly efficient method for the C-alkylation of 2-hydroxy-1,4-naphthoquinone to nitroalkenes under catalyst-free 'on water' conditions",

abstract = "C-Alkylation of 2-hydroxy-1,4-naphthoquinone to various nitroolefins was achieved under catalyst-free employing 'on water' conditions. The mechanism for the formation can be explained on the basis of dual activation of nitroalkene and 2-hydroxy-1,4-naphthoquinones via hydrogen bonding. Simple reaction conditions, high yields of the products, and environmentally benign medium are attractive features of this method.",

author = "Barange, {Deepak Kumar} and Veerababurao Kavala and Raju, {B. Rama} and Kuo, {Chun Wei} and Chi Tseng and Tu, {Yu Chen} and Yao, {Ching Fa}",

note = "Funding Information: Financial support for this work by the National Science Council of the Republic of China is gratefully acknowledged. ",

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T1 - Facile and highly efficient method for the C-alkylation of 2-hydroxy-1,4-naphthoquinone to nitroalkenes under catalyst-free 'on water' conditions

AU - Barange, Deepak Kumar

AU - Kavala, Veerababurao

AU - Raju, B. Rama

AU - Kuo, Chun Wei

AU - Tseng, Chi

AU - Tu, Yu Chen

AU - Yao, Ching Fa

N1 - Funding Information: Financial support for this work by the National Science Council of the Republic of China is gratefully acknowledged.

PY - 2009/9/9

Y1 - 2009/9/9

N2 - C-Alkylation of 2-hydroxy-1,4-naphthoquinone to various nitroolefins was achieved under catalyst-free employing 'on water' conditions. The mechanism for the formation can be explained on the basis of dual activation of nitroalkene and 2-hydroxy-1,4-naphthoquinones via hydrogen bonding. Simple reaction conditions, high yields of the products, and environmentally benign medium are attractive features of this method.

AB - C-Alkylation of 2-hydroxy-1,4-naphthoquinone to various nitroolefins was achieved under catalyst-free employing 'on water' conditions. The mechanism for the formation can be explained on the basis of dual activation of nitroalkene and 2-hydroxy-1,4-naphthoquinones via hydrogen bonding. Simple reaction conditions, high yields of the products, and environmentally benign medium are attractive features of this method.

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JO - Tetrahedron Letters

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ER -

Facile and highly efficient method for the C-alkylation of 2-hydroxy-1,4-naphthoquinone to nitroalkenes under catalyst-free 'on water' conditions

摘要

ASJC Scopus subject areas

存取文件

其它文件與鏈接

指紋

資料集

CCDC 720909: Experimental Crystal Structure Determination

引用此