Exploring the Origin of Phase-Transformation Kinetics of CsPbI3 Perovskite Nanocrystals Based on Activation Energy Measurements

Cheng Chieh Lin, Shao Ku Huang, Chung En Hsu, Yu Chen Huang, Chuan Yu Wei, Cheng Yen Wen, Shao Sian Li, Chun Wei Chen, Chia Chun Chen

    研究成果: 雜誌貢獻期刊論文同行評審

    3 引文 斯高帕斯(Scopus)


    Perovskite α-CsPbI3 nanocrystals (NCs) with a high fluorescence quantum yield (QY) typically undergo a rapid phase transformation to a low-QY δ-CsPbI3 phase, thus limiting their optoelectronic applications. In this study, organic molecule hexamethyldisilathiane (HMS) is used as a unique surfactant to greatly enhance the stability of the cubic phase of CsPbI3 NCs (HMS-CsPbI3) under ambient conditions. The reaction kinetics of the phase transformation of CsPbI3 NCs are systemically investigated through in situ photoluminescence (PL), X-ray diffraction, and transmission electron microscope (TEM) measurements under moisture. The activation energy of HMS-CsPbI3 NCs is found to be 14 times larger than that of CsPbI3 NCs capped by olyelamine (OLA-CsPbI3 NCs). According to density functional theory calculations, the bonding between HMS and CsPbI3 NCs is stronger than that between OLA and CsPbI3 NCs, preventing the subsequent phase transformation. Our study presents a clear pathway for achieving highly stable CsPbI3 NCs for future applications.

    頁(從 - 到)3287-3293
    期刊The journal of physical chemistry letters
    出版狀態已發佈 - 2020 五月 7

    ASJC Scopus subject areas

    • 材料科學(全部)
    • 物理與理論化學


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