Expanding the C 1-symmetric bicyclo[2.2.1]heptadiene ligand family: Highly enantioselective synthesis of cyclic β-aryl-substituted carbonyl compounds

Chia Chen Liu, Damodar Janmanchi, Chun Chih Chen, Hsyueh Liang Wu*

*此作品的通信作者

研究成果: 雜誌貢獻期刊論文同行評審

32 引文 斯高帕斯(Scopus)

摘要

The efficient preparation of highly enantioenriched cyclic β-aryl-substituted carbonyl compounds has been achieved through the Rh I-catalyzed asymmetric 1,4-addition of an array of arylboronic acids to cyclic α,β-unsaturated carbonyl compounds. In the presence of 0.1 or 0.5 mol-% of the Rh I/1g complex, the products of conjugate addition were isolated in 89 to 98%ee and in good to excellent yield.

原文英語
頁(從 - 到)2503-2507
頁數5
期刊European Journal of Organic Chemistry
發行號13
DOIs
出版狀態已發佈 - 2012 5月

ASJC Scopus subject areas

  • 物理與理論化學
  • 有機化學

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