Excellent diastereoselective allylation of camphor derived glyoxylic oxime ethers mediated by a Lewis acid

Neelesh A. Kulkarni; Kwunmin Chen

doi:10.1016/j.tetlet.2005.10.171

Excellent diastereoselective allylation of camphor derived glyoxylic oxime ethers mediated by a Lewis acid

Neelesh A. Kulkarni
, Kwunmin Chen^*

^*此作品的通信作者

化學系

研究成果: 雜誌貢獻 › 期刊論文 › 同行評審

16 引文斯高帕斯（Scopus）

摘要

The nucleophilic allylation of camphor derived glyoxylic oxime ethers was carried out using allyltributyltin in the presence of Sn(OTf)₂ affording the corresponding homoallylic amines in high chemical yields (up to 94%) and excellent stereoselectivities (up to >99%).

原文	英語
頁（從 - 到）	611-613
頁數	3
期刊	Tetrahedron Letters
卷	47
發行號	4
DOIs	https://doi.org/10.1016/j.tetlet.2005.10.171
出版狀態	已發佈 - 2006 1月 23

ASJC Scopus subject areas

生物化學
藥物發現
有機化學

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10.1016/j.tetlet.2005.10.171

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abstract = "The nucleophilic allylation of camphor derived glyoxylic oxime ethers was carried out using allyltributyltin in the presence of Sn(OTf)2 affording the corresponding homoallylic amines in high chemical yields (up to 94\%) and excellent stereoselectivities (up to >99\%).",

author = "Kulkarni, \{Neelesh A.\} and Kwunmin Chen",

note = "Funding Information: We thank the National Science Council of the Republic of China (NSC 94-2113-M-003-003) and the National Taiwan Normal University (ORD 93-C), for financial support of this work. The X-ray crystal data were collected and processed by National Taiwan Normal University which is gratefully acknowledged. Our gratitude is expressed to the Academic Paper Editing Clinic, NTNU.",

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AU - Kulkarni, Neelesh A.

AU - Chen, Kwunmin

N1 - Funding Information: We thank the National Science Council of the Republic of China (NSC 94-2113-M-003-003) and the National Taiwan Normal University (ORD 93-C), for financial support of this work. The X-ray crystal data were collected and processed by National Taiwan Normal University which is gratefully acknowledged. Our gratitude is expressed to the Academic Paper Editing Clinic, NTNU.

PY - 2006/1/23

Y1 - 2006/1/23

N2 - The nucleophilic allylation of camphor derived glyoxylic oxime ethers was carried out using allyltributyltin in the presence of Sn(OTf)2 affording the corresponding homoallylic amines in high chemical yields (up to 94%) and excellent stereoselectivities (up to >99%).

AB - The nucleophilic allylation of camphor derived glyoxylic oxime ethers was carried out using allyltributyltin in the presence of Sn(OTf)2 affording the corresponding homoallylic amines in high chemical yields (up to 94%) and excellent stereoselectivities (up to >99%).

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VL - 47

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ER -

Excellent diastereoselective allylation of camphor derived glyoxylic oxime ethers mediated by a Lewis acid

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