EPR Observations of Positional Disorder of the [(CH3)3NH]+ Ions in [(CH3)3NH]CdCl3

Kuo Tung Liu, Jiang Tsu Yu, Ssu Hao Lou, Yng Huey Jeng

研究成果: 雜誌貢獻文章

1 引文 (Scopus)

摘要

Two chemically inequivalent [N(CH3)3]+ radical species produced via γ-irradiation were detected by EPR in the low-temperature, orthorhombic 1 x √3 phase of [(CH3)3NH]CdCl3. This indicates a twofold, static disorder of the [(CH3)3NH]+ (TrM) ions. One of the radical species could be identified as originating from the “normal” TrM ions and the other from the “disordered” TrM ions. The EPR result also indicates that the population ratio of the “disordered” TrM ions relative to the “normal” TrM ions is temperature dependent; this ratio decreases with decreasing temperatures.

原文英語
頁(從 - 到)135-140
頁數6
期刊Journal of the Physical Society of Japan
63
發行號1
DOIs
出版狀態已發佈 - 1994 一月 1

指紋

disorders
ions
ion temperature
irradiation
temperature

ASJC Scopus subject areas

  • Physics and Astronomy(all)

引用此文

EPR Observations of Positional Disorder of the [(CH3)3NH]+ Ions in [(CH3)3NH]CdCl3 . / Liu, Kuo Tung; Yu, Jiang Tsu; Lou, Ssu Hao; Jeng, Yng Huey.

於: Journal of the Physical Society of Japan, 卷 63, 編號 1, 01.01.1994, p. 135-140.

研究成果: 雜誌貢獻文章

Liu, Kuo Tung ; Yu, Jiang Tsu ; Lou, Ssu Hao ; Jeng, Yng Huey. / EPR Observations of Positional Disorder of the [(CH3)3NH]+ Ions in [(CH3)3NH]CdCl3 於: Journal of the Physical Society of Japan. 1994 ; 卷 63, 編號 1. 頁 135-140.
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