Epoxidation of Chiral Camphor N-Enoylpyrazolidinones with Methyl(trifluoromethyl)dioxirane and Urea Hydrogen Peroxide/Acid Anhydride: Reversal of Stereoselectivity

Chai Ling Fan, Wei Der Lee, Nai Wei Teng, Ying Chieh Sun*, Kwunmin Chen

*此作品的通信作者

研究成果: 雜誌貢獻期刊論文同行評審

34 引文 斯高帕斯(Scopus)

摘要

Both diastereomeric isomers of epoxides with high optical purity are obtained when camphor N-methacryl-oylpyrazolidinone (1a) and N-tigloylpyrazolidinone (1b) are treated with a urea hydrogen peroxide/TFAA and methyl-(trifluoromethyl)dioxirane, respectively.

原文英語
頁(從 - 到)9816-9818
頁數3
期刊Journal of Organic Chemistry
68
發行號25
DOIs
出版狀態已發佈 - 2003 12月 12

ASJC Scopus subject areas

  • 有機化學

指紋

深入研究「Epoxidation of Chiral Camphor N-Enoylpyrazolidinones with Methyl(trifluoromethyl)dioxirane and Urea Hydrogen Peroxide/Acid Anhydride: Reversal of Stereoselectivity」主題。共同形成了獨特的指紋。

引用此