摘要
matrix presented Reaction of various N-enoyl oxazolidinones 5a-f with N-aminophthalimide and lead tetraacetate in the presence of camphor-derived chiral ligands provides the desired N-phthalimidoaziridines 6a-f in good to high enantiomeric excess (67-95% ee) at 0°C within 15 min. The absolute stereochemistry of the corresponding aziridine derivatives was established by chemical correlations.
| 原文 | 英語 |
|---|---|
| 頁（從 - 到） | 1107-1109 |
| 頁數 | 3 |
| 期刊 | Organic Letters |
| 卷 | 4 |
| 發行號 | 7 |
| DOIs | |
| 出版狀態 | 已發佈 - 2002 4月 4 |
ASJC Scopus subject areas
- 生物化學
- 物理與理論化學
- 有機化學
指紋
深入研究「Enantioselective Aziridination of Alkenes with N-Aminophthalimide in the Presence of Lead Tetraacetate-Mediated Chiral Ligand」主題。共同形成了獨特的指紋。資料集
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CCDC 188424: Experimental Crystal Structure Determination
Yang, K.-S. (Creator) & Chen, K. (Creator), Unknown Publisher, 2003
DOI: 10.5517/cc6b26s, http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/cc6b26s&sid=DataCite
資料集: Dataset
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CCDC 188426: Experimental Crystal Structure Determination
Yang, K.-S. (Creator) & Chen, K. (Creator), Unknown Publisher, 2003
DOI: 10.5517/cc6b28v, http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/cc6b28v&sid=DataCite
資料集: Dataset
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CCDC 188425: Experimental Crystal Structure Determination
Yang, K.-S. (Creator) & Chen, K. (Creator), Unknown Publisher, 2003
DOI: 10.5517/cc6b27t, http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/cc6b27t&sid=DataCite
資料集: Dataset