Electrospun membranes of imidazole-grafted PVDF-HFP polymeric ionic liquids for highly efficient quasi-solid-state dye-sensitized solar cells

Hao Wei Pang, Hsin Fu Yu, Yi June Huang, Chun Ting Li, Kuo Chuan Ho*

*此作品的通信作者

研究成果: 雜誌貢獻期刊論文同行評審

34 引文 斯高帕斯(Scopus)

摘要

Three novel polymeric ionic liquids (PILs), denoted as PFII-F, PFII-E, and PFII-S, are successfully synthesized by grafting different molar ratios (one-fourth, one eighth, and one sixteenth, respectively) of 1-butylimidazolium iodide onto poly(vinylidene fluoride-co-hexafluoropropylene) (PVDF-HFP). These PFII PILs are fabricated as polymer membranes via a simple electrospinning technique, which are used as the electrolyte for quasi-solid-state (QSS) dye-sensitized solar cells (DSSCs). The PFII membranes have multiple functions including: (1) encapsulation of the liquid electrolyte with good charge transfer and ionic conductivity properties, (2) chelation of Li+ through the lone pair electrons on their fluoride atoms, and (3) filling the dye-uncovered TiO2 surface with their imidazolium segment. Function (1) endows DSSCs with prominent long-term stability, while functions (2) and (3) suppress the dark current. The best QSS-DSSC with the PFII-F membrane shows a larger open-circuit voltage (VOC), comparable short-circuit current density (JSC), better power conversion efficiency (η) of 9.26%, and superior long-term stability (up to 97% of its initial η) over 1500 h compared to the cell with standard liquid electrolyte (8.63%).

原文英語
頁(從 - 到)14215-14223
頁數9
期刊Journal of Materials Chemistry A
6
發行號29
DOIs
出版狀態已發佈 - 2018
對外發佈

ASJC Scopus subject areas

  • 一般化學
  • 可再生能源、永續發展與環境
  • 一般材料科學

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