Effects of doping concentration and annealing temperature on properties of highly-oriented Al-doped ZnO films

Shou Yi Kuo*, Wei Chun Chen, Fang I. Lai, Chin Pao Cheng, Hao Chung Kuo, Shing Chung Wang, Wen Feng Hsieh


研究成果: 雜誌貢獻會議論文同行評審

376 引文 斯高帕斯(Scopus)


Transparent and conductive high-preferential c-axis-oriented Al-doped zinc oxide (ZnO:Al, AZO) thin films have been prepared by the sol-gel route. Film deposition was performed by spin-coating technique on Si(1 0 0) and glass substrate. Structural, electrical and optical properties were performed by XRD, SEM, four-point probe, photoluminescence (PL) and UV-VIS spectrum measurements. The effects of annealing temperature and dopant concentration on the structural and optical properties are well discussed. It was found that both annealing temperature and doping concentration alter the microstructures of AZO films. Also, PL spectra show two main peaks centered at about 380 nm (UV) and 520 nm (green). The variation of UV-to-green band emission was greatly influenced by annealing temperatures and doping concentration. Reduction in intensity ratio of UV-to-green might possibly originate from the formation of Al-O bonds and localized Al-impurity states. The minimum sheet resistance of 104 Ω/□ was obtained for the film doped with 1.6 mol% Al, annealed at 750°C. Meanwhile, all AZO films deposited on glass are very transparent, between 80% and 95% transmittance, within the visible wavelength region. These results imply that the doping concentration did not have significant influence on transparent properties, but improve the electrical conductivity and diversify emission features.

頁(從 - 到)78-84
期刊Journal of Crystal Growth
出版狀態已發佈 - 2006 1月 18
事件Proceedings of the International Conference on Materials for Advanced Technologies (ICMAT 2005) Symposium N ZnO and Related Materials -
持續時間: 2005 7月 32005 7月 8

ASJC Scopus subject areas

  • 凝聚態物理學
  • 無機化學
  • 材料化學


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