(Dithio-benzoato-κ2 S,S′)[hydridotris(pyrazol-1-yl-N κ2)borato](triphenyl-phosphine-P)ruthenium(II)

Chia Her Lin, Yao Ren Liang, Hung Chun Tong, Yih Hsing Lo, Ting Shen Kuo

研究成果: 雜誌貢獻期刊論文同行評審

2 引文 斯高帕斯(Scopus)

摘要

Reaction of [Ru(Tp)Cl(PPh3)2] (Tp = hydridotrispyrazolyl-borate) with ammonium dithio-benzoate in methanol leads to the formation of the title compound, [Ru(C9H10BN6)(C7H5S2)(C18H15P)]. In the crystal structure, the Ru atom is coordinated by three N atoms of the Tp ligand, one P atom of the triphenyl-phosphine ligand and the two S atoms of the dithio-benzoate ligand within a slightly distorted octa-hedron. The Ru - S bonds are slightly different [2.321 (1) and 2.396 (1) Å] and the average N - Ru - N angle is 86.31°.

原文英語
頁(從 - 到)m1535
期刊Acta Crystallographica Section E: Structure Reports Online
64
發行號12
DOIs
出版狀態已發佈 - 2008
對外發佈

ASJC Scopus subject areas

  • 化學 (全部)
  • 材料科學(全部)
  • 凝聚態物理學

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