Direct β-acylation of 2-arylidene-1,3-indandiones with acyl chlorides catalyzed by organophosphanes

Chia Jui Lee; Chia Ning Sheu; Cheng Che Tsai; Zong Ze Wu; Wenwei Lin

doi:10.1039/c3cc45201h

Direct β-acylation of 2-arylidene-1,3-indandiones with acyl chlorides catalyzed by organophosphanes

Chia Jui Lee, Chia Ning Sheu, Cheng Che Tsai, Zong Ze Wu, Wenwei Lin^*

^*此作品的通信作者

化學系

研究成果: 雜誌貢獻 › 期刊論文 › 同行評審

34 引文斯高帕斯（Scopus）

摘要

We have developed an organophosphane-catalyzed direct β-acylation of a series of conjugated systems bearing ketone, amide and ester functionalities using acyl chlorides as trapping reagents. A wide variety of highly functional ketone derivatives were generated efficiently under very mild conditions with high yields according to our protocol. Our adducts can even be utilized as important building blocks for the synthesis of functional tri/tetracyclic pyridazine derivatives.

原文	英語
頁（從 - 到）	5304-5306
頁數	3
期刊	Chemical Communications
卷	50
發行號	40
DOIs	https://doi.org/10.1039/c3cc45201h
出版狀態	已發佈 - 2014 4月 22

ASJC Scopus subject areas

催化
電子、光磁材料
陶瓷和複合材料
一般化學
表面、塗料和薄膜
金屬和合金
材料化學

存取文件

10.1039/c3cc45201h

其它文件與鏈接

Link to publication in Scopus

CCDC 937197: Experimental Crystal Structure Determination
Lee, C. (Creator), Sheu, C. (Creator), Tsai, C. (Creator), Wu, Z. (Creator) & Lin, W. (Creator), Unknown Publisher, 2013
DOI: 10.5517/cc10g75w, http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/cc10g75w&sid=DataCite
資料集: Dataset
CCDC 935874: Experimental Crystal Structure Determination
Lee, C. (Creator), Sheu, C. (Creator), Tsai, C. (Creator), Wu, Z. (Creator) & Lin, W. (Creator), Unknown Publisher, 2013
DOI: 10.5517/cc10dvhr, http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/cc10dvhr&sid=DataCite
資料集: Dataset
CCDC 935872: Experimental Crystal Structure Determination
Lee, C. (Creator), Sheu, C. (Creator), Tsai, C. (Creator), Wu, Z. (Creator) & Lin, W. (Creator), Unknown Publisher, 2013
DOI: 10.5517/cc10dvfp, http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/cc10dvfp&sid=DataCite
資料集: Dataset

引用此

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abstract = "We have developed an organophosphane-catalyzed direct β-acylation of a series of conjugated systems bearing ketone, amide and ester functionalities using acyl chlorides as trapping reagents. A wide variety of highly functional ketone derivatives were generated efficiently under very mild conditions with high yields according to our protocol. Our adducts can even be utilized as important building blocks for the synthesis of functional tri/tetracyclic pyridazine derivatives.",

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AU - Lee, Chia Jui

AU - Sheu, Chia Ning

AU - Tsai, Cheng Che

AU - Wu, Zong Ze

AU - Lin, Wenwei

PY - 2014/4/22

Y1 - 2014/4/22

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AB - We have developed an organophosphane-catalyzed direct β-acylation of a series of conjugated systems bearing ketone, amide and ester functionalities using acyl chlorides as trapping reagents. A wide variety of highly functional ketone derivatives were generated efficiently under very mild conditions with high yields according to our protocol. Our adducts can even be utilized as important building blocks for the synthesis of functional tri/tetracyclic pyridazine derivatives.

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ER -

Direct β-acylation of 2-arylidene-1,3-indandiones with acyl chlorides catalyzed by organophosphanes

摘要

ASJC Scopus subject areas

存取文件

其它文件與鏈接

指紋

資料集

CCDC 937197: Experimental Crystal Structure Determination

CCDC 935874: Experimental Crystal Structure Determination

CCDC 935872: Experimental Crystal Structure Determination

引用此