Dimensionally reduced one-dimensional chains of TiSe2

Tianyang Li, Yi Hsin Liu, Spencer Porter, Joshua E. Goldberger*

*此作品的通信作者

研究成果: 雜誌貢獻期刊論文同行評審

12 引文 斯高帕斯(Scopus)

摘要

A study was conducted to demonstrate the formation and use of dimensionally reduced one-dimensional chains of TiS2. TiS2 was synthesized using TiCl4 and elemental Se as precursors. Reactants were annealed in a Parr reactor at 220 °C for 5 days and TiSeO(en) was synthesized similarly except for Se powder being dissolved in excess en without NaBH4 at 180 °C. The Ti:Se stoichiometry for the two samples was confirmed via X-ray fluorescence and the 2:8:2 C:H:N ratio was confirmed by elemental analysis. Investigations revealed that TiSe2(en) and TiSeO(en) had a similar crystalline structure to TiS2(en). The crystal structures were determined via Rietveld refinement of X-ray powder diffraction patterns using the TOPAS Academic software package.

原文英語
頁(從 - 到)1477-1479
頁數3
期刊Chemistry of Materials
25
發行號9
DOIs
出版狀態已發佈 - 2013 5月 14
對外發佈

ASJC Scopus subject areas

  • 一般化學
  • 一般化學工程
  • 材料化學

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