Dielectric, ionic conductivity and structural phase transitions studies of (NH4)3H(SO4)2 crystal

R. H. Chen*, T. M. Chen, Ching-Song Shern

*此作品的通信作者

研究成果: 雜誌貢獻期刊論文同行評審

32 引文 斯高帕斯(Scopus)

摘要

The temperature and frequency dependent complex impedance of (NH4)3H(SO4)2 crystals was measured. The measurements have been performed in the temperature range from 27 to 220 °C along the c*-axis of the room temperature phase. AC frequencies between 100 Hz and 5 MHz were applied. The crystals investigated in this work revealed two structural phase transitions above room temperature. The crystal becomes a fast ionic conductor in both the high temperature phases. The dielectric properties of the sample crystal in different phases were analyzed. The behavior of protonic conduction was explained by means of a power law σ′(ω) = σ(0)+Bω+s$/, where ω is the frequency of the applied AC electric field. The exponent s, decreases from 0.7 to 0.3 with increasing temperature for the room temperature phase but becomes almost constant (≤0.1) in the fast ionic phases. Both, the electrical conductivity and relaxation appear to be thermally activated.

原文英語
頁(從 - 到)1399-1406
頁數8
期刊Journal of Physics and Chemistry of Solids
61
發行號9
DOIs
出版狀態已發佈 - 2000 九月

ASJC Scopus subject areas

  • 化學 (全部)
  • 材料科學(全部)
  • 凝聚態物理學

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