Diastereoselective three component reaction of N-glyoxyloyl camphorpyrazolidinone, amine and allyltributylstannane: Facile synthesis of homoallylic amines

Chih Liang Chang; Kwun Min Chen

doi:10.1002/jccs.200700224

Diastereoselective three component reaction of N-glyoxyloyl camphorpyrazolidinone, amine and allyltributylstannane: Facile synthesis of homoallylic amines

Chih Liang Chang, Kwun Min Chen^*

^*此作品的通信作者

化學系

研究成果: 雜誌貢獻 › 期刊論文 › 同行評審

1 引文斯高帕斯（Scopus）

摘要

Diastereoselective allylation of imine derived from N-glyoxyloyl camphorpyrazolidinone and amines was treated with allyltributylstannane in the presence of triflic acid. The corresponding optically enriched homoallylic amines were obtained in reasonable to high material yields and with practical levels of stereoselectivity in 10 min at ambient temperature.

原文	英語
頁（從 - 到）	1591-1594
頁數	4
期刊	Journal of the Chinese Chemical Society
卷	54
發行號	6
DOIs	https://doi.org/10.1002/jccs.200700224
出版狀態	已發佈 - 2007

ASJC Scopus subject areas

一般化學

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10.1002/jccs.200700224

其它文件與鏈接

Link to publication in Scopus

CCDC 639469: Experimental Crystal Structure Determination
Chang, C. (Creator) & Chen, K. (Creator), Unknown Publisher, 2008
DOI: 10.5517/ccpgf1l, http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/ccpgf1l&sid=DataCite
資料集: Dataset

引用此

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title = "Diastereoselective three component reaction of N-glyoxyloyl camphorpyrazolidinone, amine and allyltributylstannane: Facile synthesis of homoallylic amines",

abstract = "Diastereoselective allylation of imine derived from N-glyoxyloyl camphorpyrazolidinone and amines was treated with allyltributylstannane in the presence of triflic acid. The corresponding optically enriched homoallylic amines were obtained in reasonable to high material yields and with practical levels of stereoselectivity in 10 min at ambient temperature.",

keywords = "Allylation, Camphorpyrazolidinone, Chiral auxiliary, Diastereoselective, Homoallylic amine, Stereoselectivity",

author = "Chang, {Chih Liang} and Chen, {Kwun Min}",

year = "2007",

doi = "10.1002/jccs.200700224",

language = "English",

volume = "54",

pages = "1591--1594",

journal = "Journal of the Chinese Chemical Society",

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publisher = "Chinese Chemical Society",

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T1 - Diastereoselective three component reaction of N-glyoxyloyl camphorpyrazolidinone, amine and allyltributylstannane

T2 - Facile synthesis of homoallylic amines

AU - Chang, Chih Liang

AU - Chen, Kwun Min

PY - 2007

Y1 - 2007

N2 - Diastereoselective allylation of imine derived from N-glyoxyloyl camphorpyrazolidinone and amines was treated with allyltributylstannane in the presence of triflic acid. The corresponding optically enriched homoallylic amines were obtained in reasonable to high material yields and with practical levels of stereoselectivity in 10 min at ambient temperature.

AB - Diastereoselective allylation of imine derived from N-glyoxyloyl camphorpyrazolidinone and amines was treated with allyltributylstannane in the presence of triflic acid. The corresponding optically enriched homoallylic amines were obtained in reasonable to high material yields and with practical levels of stereoselectivity in 10 min at ambient temperature.

KW - Allylation

KW - Camphorpyrazolidinone

KW - Chiral auxiliary

KW - Diastereoselective

KW - Homoallylic amine

KW - Stereoselectivity

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U2 - 10.1002/jccs.200700224

DO - 10.1002/jccs.200700224

M3 - Article

AN - SCOPUS:38349081729

SN - 0009-4536

VL - 54

SP - 1591

EP - 1594

JO - Journal of the Chinese Chemical Society

JF - Journal of the Chinese Chemical Society

IS - 6

ER -

Diastereoselective three component reaction of N-glyoxyloyl camphorpyrazolidinone, amine and allyltributylstannane: Facile synthesis of homoallylic amines

摘要

ASJC Scopus subject areas

存取文件

其它文件與鏈接

指紋

資料集

CCDC 639469: Experimental Crystal Structure Determination

引用此