TY - JOUR
T1 - (C4H12N2)3[Ga 4(OH)2(H2PO4)2(HPO 4)4(PO4)2]
T2 - A new organically templated gallium phosphate
AU - Lin, Chia Her
AU - Wang, Sue Lein
PY - 2006/12
Y1 - 2006/12
N2 - The solvothermal reaction of gallium oxide with phosphoric acid in water/ethylene glycol in the presence of piperazine gave the title compound, bis(piperazinium) bis(dihydrogenphosphato)tetra-μ2- hydrogenphosphato-di-μ3-hydroxo-di-μ3-phosphato- tetragallate(III), (C4H12N2) 3[Ga4(OH)2(H2PO4) 2-(HPO4)4(PO4)2]. The compound is isostructural with its FeIII analogue, and contains one-dimensional anionic chains with piperazinium cations lying between them. The tetranuclear anionic building blocks and the piperazinium cations lie on inversion centres.
AB - The solvothermal reaction of gallium oxide with phosphoric acid in water/ethylene glycol in the presence of piperazine gave the title compound, bis(piperazinium) bis(dihydrogenphosphato)tetra-μ2- hydrogenphosphato-di-μ3-hydroxo-di-μ3-phosphato- tetragallate(III), (C4H12N2) 3[Ga4(OH)2(H2PO4) 2-(HPO4)4(PO4)2]. The compound is isostructural with its FeIII analogue, and contains one-dimensional anionic chains with piperazinium cations lying between them. The tetranuclear anionic building blocks and the piperazinium cations lie on inversion centres.
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U2 - 10.1107/S1600536806045375
DO - 10.1107/S1600536806045375
M3 - Article
AN - SCOPUS:33845388168
VL - 62
SP - m3289-m3290
JO - Acta Crystallographica Section E: Structure Reports Online
JF - Acta Crystallographica Section E: Structure Reports Online
SN - 1600-5368
IS - 12
ER -