Controlling morphology and crystallite size of Cu(In0.7Ga 0.3)Se2 nano-crystals synthesized using a heating-up method

Wei Hsiang Hsu; Hsing I. Hsiang; Chih Ta Chia; Fu Su Yen

doi:10.1016/j.jssc.2013.09.033

Controlling morphology and crystallite size of Cu(In_0.7Ga _0.3)Se₂ nano-crystals synthesized using a heating-up method

Wei Hsiang Hsu, Hsing I. Hsiang^*, Chih Ta Chia, Fu Su Yen

^*此作品的通信作者

物理學系

研究成果: 雜誌貢獻 › 期刊論文 › 同行評審

13 引文斯高帕斯（Scopus）

摘要

CuIn_0.7Ga_0.3Se₂(CIGS) nano-crystals were successfully synthesized via a heating-up process. The non-coordinating solvent (1-octadecene) and selenium/cations ratio effects on the crystalline phase and crystallite size of CIGS nano-crystallites were investigated. It was observed that the CIGS nano-crystallite morphology changed from sheet into spherical shape as the amount of 1-octadecene addition was increased. CIGS nano-crystals were obtained in 9-20 nm sizes as the selenium/cations ratio increased. These results suggest that the monomer reactivity in the solution can be adjusted by changing the solvent type and selenium/cations ratio, hence affecting the crystallite size and distribution.

原文	英語
頁（從 - 到）	1-8
頁數	8
期刊	Journal of Solid State Chemistry
卷	208
DOIs	https://doi.org/10.1016/j.jssc.2013.09.033
出版狀態	已發佈 - 2013

ASJC Scopus subject areas

電子、光磁材料
陶瓷和複合材料
凝聚態物理學
物理與理論化學
無機化學
材料化學

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10.1016/j.jssc.2013.09.033

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@article{ab00c5542283432c9ef2d89cad00a437,

title = "Controlling morphology and crystallite size of Cu(In0.7Ga 0.3)Se2 nano-crystals synthesized using a heating-up method",

abstract = "CuIn0.7Ga0.3Se2(CIGS) nano-crystals were successfully synthesized via a heating-up process. The non-coordinating solvent (1-octadecene) and selenium/cations ratio effects on the crystalline phase and crystallite size of CIGS nano-crystallites were investigated. It was observed that the CIGS nano-crystallite morphology changed from sheet into spherical shape as the amount of 1-octadecene addition was increased. CIGS nano-crystals were obtained in 9-20 nm sizes as the selenium/cations ratio increased. These results suggest that the monomer reactivity in the solution can be adjusted by changing the solvent type and selenium/cations ratio, hence affecting the crystallite size and distribution.",

keywords = "Copper indium gallium diselenide, Heating-up process, Nano-crystals, Size controlled",

author = "Hsu, {Wei Hsiang} and Hsiang, {Hsing I.} and Chia, {Chih Ta} and Yen, {Fu Su}",

note = "Funding Information: This work was financially co-sponsored by the Ministry of Economic Affairs of the Republic of China ( 101-EC-17-A-10-S1-187 ) and National Science Council of the Republic of China ( NSC 101-ET-E-006-002-ET ).",

year = "2013",

doi = "10.1016/j.jssc.2013.09.033",

language = "English",

volume = "208",

pages = "1--8",

journal = "Journal of Solid State Chemistry",

issn = "0022-4596",

publisher = "Academic Press Inc.",

}

TY - JOUR

T1 - Controlling morphology and crystallite size of Cu(In0.7Ga 0.3)Se2 nano-crystals synthesized using a heating-up method

AU - Hsu, Wei Hsiang

AU - Hsiang, Hsing I.

AU - Chia, Chih Ta

AU - Yen, Fu Su

N1 - Funding Information: This work was financially co-sponsored by the Ministry of Economic Affairs of the Republic of China ( 101-EC-17-A-10-S1-187 ) and National Science Council of the Republic of China ( NSC 101-ET-E-006-002-ET ).

PY - 2013

Y1 - 2013

N2 - CuIn0.7Ga0.3Se2(CIGS) nano-crystals were successfully synthesized via a heating-up process. The non-coordinating solvent (1-octadecene) and selenium/cations ratio effects on the crystalline phase and crystallite size of CIGS nano-crystallites were investigated. It was observed that the CIGS nano-crystallite morphology changed from sheet into spherical shape as the amount of 1-octadecene addition was increased. CIGS nano-crystals were obtained in 9-20 nm sizes as the selenium/cations ratio increased. These results suggest that the monomer reactivity in the solution can be adjusted by changing the solvent type and selenium/cations ratio, hence affecting the crystallite size and distribution.

AB - CuIn0.7Ga0.3Se2(CIGS) nano-crystals were successfully synthesized via a heating-up process. The non-coordinating solvent (1-octadecene) and selenium/cations ratio effects on the crystalline phase and crystallite size of CIGS nano-crystallites were investigated. It was observed that the CIGS nano-crystallite morphology changed from sheet into spherical shape as the amount of 1-octadecene addition was increased. CIGS nano-crystals were obtained in 9-20 nm sizes as the selenium/cations ratio increased. These results suggest that the monomer reactivity in the solution can be adjusted by changing the solvent type and selenium/cations ratio, hence affecting the crystallite size and distribution.

KW - Copper indium gallium diselenide

KW - Heating-up process

KW - Nano-crystals

KW - Size controlled

UR - http://www.scopus.com/inward/record.url?scp=84885074776&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=84885074776&partnerID=8YFLogxK

U2 - 10.1016/j.jssc.2013.09.033

DO - 10.1016/j.jssc.2013.09.033

M3 - Article

AN - SCOPUS:84885074776

SN - 0022-4596

VL - 208

SP - 1

EP - 8

JO - Journal of Solid State Chemistry

JF - Journal of Solid State Chemistry

ER -

Controlling morphology and crystallite size of Cu(In0.7Ga 0.3)Se2 nano-crystals synthesized using a heating-up method

摘要

ASJC Scopus subject areas

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Controlling morphology and crystallite size of Cu(In_0.7Ga _0.3)Se₂ nano-crystals synthesized using a heating-up method