摘要
A series of substituted nitrogen-containing 9-membered epoxy vinyl ethers has been constructed from easily available 5-aza-2,3-epoxy-7-yn-1-ols. Attack of the hydroxyl group onto the gold(I)-activated alkyne gave the postulated 9-membered allylic vinyl ether gold intermediate which underwent protodeauration affording the 9-membered epoxy vinyl ethers.
| 原文 | 英語 |
|---|---|
| 頁（從 - 到） | 1281-1288 |
| 頁數 | 8 |
| 期刊 | Journal of the Chinese Chemical Society |
| 卷 | 61 |
| 發行號 | 12 |
| DOIs | |
| 出版狀態 | 已發佈 - 2014 七月 25 |
ASJC Scopus subject areas
- Chemistry(all)
指紋 深入研究「Construction of nitrogen-containing 9-membered ring epoxy vinyl ethers via gold(I)-catalyzed intramolecular cyclization reactions of acyclic 5-aza-2,3-epoxy-7-yn-1-ols」主題。共同形成了獨特的指紋。
引用此
Lin, H. H., Chen, Y. J., Liao, K. Y., & Yeh, M. C. P. (2014). Construction of nitrogen-containing 9-membered ring epoxy vinyl ethers via gold(I)-catalyzed intramolecular cyclization reactions of acyclic 5-aza-2,3-epoxy-7-yn-1-ols. Journal of the Chinese Chemical Society, 61(12), 1281-1288. https://doi.org/10.1002/jccs.201400121