Construction of nitrogen-containing 9-membered ring epoxy vinyl ethers via gold(I)-catalyzed intramolecular cyclization reactions of acyclic 5-aza-2,3-epoxy-7-yn-1-ols

Hsin Hui Lin, Yi Ju Chen, Kuan Yu Liao, Ming Chang P. Yeh

研究成果: 雜誌貢獻文章

摘要

A series of substituted nitrogen-containing 9-membered epoxy vinyl ethers has been constructed from easily available 5-aza-2,3-epoxy-7-yn-1-ols. Attack of the hydroxyl group onto the gold(I)-activated alkyne gave the postulated 9-membered allylic vinyl ether gold intermediate which underwent protodeauration affording the 9-membered epoxy vinyl ethers.

原文英語
頁(從 - 到)1281-1288
頁數8
期刊Journal of the Chinese Chemical Society
61
發行號12
DOIs
出版狀態已發佈 - 2014 七月 25

ASJC Scopus subject areas

  • Chemistry(all)

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