Construction of fused, bridged, and spiro bicyclic skeletons via nickel-catalyzed intramolecular cyclization of cyclic 1,3-dienes and a tethered aldehyde

Ming Chang P. Yeh; Jong Hao Liang; Yi Lin Jiang; Ming Shan Tsai

doi:10.1016/S0040-4020(03)00512-X

Construction of fused, bridged, and spiro bicyclic skeletons via nickel-catalyzed intramolecular cyclization of cyclic 1,3-dienes and a tethered aldehyde

Ming Chang P. Yeh^*
, Jong Hao Liang
, Yi Lin Jiang
, Ming Shan Tsai

^*此作品的通信作者

化學系

研究成果: 雜誌貢獻 › 期刊論文 › 同行評審

11 引文斯高帕斯（Scopus）

摘要

Nickel-catalyzed intramolecular cyclization of cyclohexa-1,3-dienes and an aldehyde in a chain produced fused, bridged or spiro bicyclic skeletons depending on the length of the tether. This chemistry can be extended to cyclohepta-1,3-dienes and cyclohepta-1,3,5-trienes having an aldehyde moiety on the side chain.

原文	英語
頁（從 - 到）	3409-3415
頁數	7
期刊	Tetrahedron
卷	59
發行號	19
DOIs	https://doi.org/10.1016/S0040-4020(03)00512-X
出版狀態	已發佈 - 2003 5月 5

ASJC Scopus subject areas

生物化學
藥物發現
有機化學

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10.1016/S0040-4020(03)00512-X

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@article{81604e904177435ba7a737f961c9e3c2,

title = "Construction of fused, bridged, and spiro bicyclic skeletons via nickel-catalyzed intramolecular cyclization of cyclic 1,3-dienes and a tethered aldehyde",

abstract = "Nickel-catalyzed intramolecular cyclization of cyclohexa-1,3-dienes and an aldehyde in a chain produced fused, bridged or spiro bicyclic skeletons depending on the length of the tether. This chemistry can be extended to cyclohepta-1,3-dienes and cyclohepta-1,3,5-trienes having an aldehyde moiety on the side chain.",

keywords = "Cyclic 1,3-dienes, Fused, bridged, and spiro carbobicycles, Nickel, Stereoselectivity",

author = "Yeh, \{Ming Chang P.\} and Liang, \{Jong Hao\} and Jiang, \{Yi Lin\} and Tsai, \{Ming Shan\}",

note = "Funding Information: This work was supported by grants from National Taiwan Normal University (ORD 92-2) and the National Science Council (NSC 90-2113-M-003-008).",

year = "2003",

month = may,

day = "5",

doi = "10.1016/S0040-4020(03)00512-X",

language = "English",

volume = "59",

pages = "3409--3415",

journal = "Tetrahedron",

issn = "0040-4020",

publisher = "Elsevier Limited",

number = "19",

}

TY - JOUR

T1 - Construction of fused, bridged, and spiro bicyclic skeletons via nickel-catalyzed intramolecular cyclization of cyclic 1,3-dienes and a tethered aldehyde

AU - Yeh, Ming Chang P.

AU - Liang, Jong Hao

AU - Jiang, Yi Lin

AU - Tsai, Ming Shan

N1 - Funding Information: This work was supported by grants from National Taiwan Normal University (ORD 92-2) and the National Science Council (NSC 90-2113-M-003-008).

PY - 2003/5/5

Y1 - 2003/5/5

N2 - Nickel-catalyzed intramolecular cyclization of cyclohexa-1,3-dienes and an aldehyde in a chain produced fused, bridged or spiro bicyclic skeletons depending on the length of the tether. This chemistry can be extended to cyclohepta-1,3-dienes and cyclohepta-1,3,5-trienes having an aldehyde moiety on the side chain.

AB - Nickel-catalyzed intramolecular cyclization of cyclohexa-1,3-dienes and an aldehyde in a chain produced fused, bridged or spiro bicyclic skeletons depending on the length of the tether. This chemistry can be extended to cyclohepta-1,3-dienes and cyclohepta-1,3,5-trienes having an aldehyde moiety on the side chain.

KW - Cyclic 1,3-dienes

KW - Fused, bridged, and spiro carbobicycles

KW - Nickel

KW - Stereoselectivity

UR - https://www.scopus.com/pages/publications/0037420842

UR - https://www.scopus.com/pages/publications/0037420842#tab=citedBy

U2 - 10.1016/S0040-4020(03)00512-X

DO - 10.1016/S0040-4020(03)00512-X

M3 - Article

AN - SCOPUS:0037420842

SN - 0040-4020

VL - 59

SP - 3409

EP - 3415

JO - Tetrahedron

JF - Tetrahedron

IS - 19

ER -

Construction of fused, bridged, and spiro bicyclic skeletons via nickel-catalyzed intramolecular cyclization of cyclic 1,3-dienes and a tethered aldehyde

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